Poly(methimazolyl)silanes: Syntheses and molecular structures

Jörg Wagler; Thomas Heine; Anthony F. Hill

doi:10.1021/om1004989

Poly(methimazolyl)silanes: Syntheses and molecular structures

Jörg Wagler, Thomas Heine, Anthony F. Hill

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

A new class of multidentate "scorpionate" ligands is readily obtained from the reactions of methimazole with a range of organochlorosilanes. A recurrent structural feature to emerge is the intramolecular S-capping of the tetrahedral inner Si coordination spheres, the nature of which is responsive to the substitution pattern at silicon.

Original language	English
Pages (from-to)	5607-5613
Number of pages	7
Journal	Organometallics
Volume	29
Issue number	21
DOIs	https://doi.org/10.1021/om1004989
Publication status	Published - 2010 Nov 8

All Science Journal Classification (ASJC) codes

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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10.1021/om1004989

Cite this

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T2 - Syntheses and molecular structures

AU - Wagler, Jörg

AU - Heine, Thomas

AU - Hill, Anthony F.

PY - 2010/11/8

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N2 - A new class of multidentate "scorpionate" ligands is readily obtained from the reactions of methimazole with a range of organochlorosilanes. A recurrent structural feature to emerge is the intramolecular S-capping of the tetrahedral inner Si coordination spheres, the nature of which is responsive to the substitution pattern at silicon.

AB - A new class of multidentate "scorpionate" ligands is readily obtained from the reactions of methimazole with a range of organochlorosilanes. A recurrent structural feature to emerge is the intramolecular S-capping of the tetrahedral inner Si coordination spheres, the nature of which is responsive to the substitution pattern at silicon.

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JO - Organometallics

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ER -

Poly(methimazolyl)silanes: Syntheses and molecular structures

Abstract

All Science Journal Classification (ASJC) codes

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