Phase-change like process through bond switching in distorted and resonantly bonded crystal

Won Jun Yang, Hanjin Park, Da Sol Kim, Taewoo Ha, Seung Jong Park, Min Ahn, Jae Hoon Kim, Young Kyun Kwon, Mann Ho Cho

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4 Citations (Scopus)


Although some methods to improve phase-change memory efficiency have been proposed, an effective experimental approach to induce a phase-change like process without external heat energy has not yet been reported. Herein we have shown that GeTe is a prototype phase-change material, which can exhibit a non-thermal phase-change-like process under uniaxial stress. Due to its structural characteristics like directional structural instability and resonance bonding under 1% uniaxial stress, we observed that bond switching in the GeTe film between short and long bonds is possible. Due to this phase change, GeTe displays the same phase-change as crystal layer rotation. Crystal layer rotation has not been observed in the conventional phase change process using intermediate states, but it is related to the structural characteristics required for maintaining local coordination. Moreover, since the resonance bonding characteristics are effectively turned off upon applying uniaxial stress, the high-frequency dielectric constant can be significantly decreased. Our results also show that the most significant process in the non-thermal phase transition of phase-change materials is the modulation of the lattice relaxation process after the initial perturbation, rather than the method inducing the perturbation itself. Finally, these consequences suggest that a new type of phase-change memory is possible through changes in the optical properties under stress.

Original languageEnglish
Article number12816
JournalScientific reports
Issue number1
Publication statusPublished - 2019 Dec 1

Bibliographical note

Funding Information:
This research was supported by the National Research Foundation of Korea (NRF) grant funded by the Korea government (No. 2018R1A2A1A05023214) and the Ministry of Trade, Industry & Energy (MOTIE) in Korea (Project No. 10080625) and Nano Material Technology Development Program through the National Research foundation of Korea (NRF) funded by the Ministry of Science, ICT and Future Planning (NRF-2016M3A7B4910398). The authors are grateful for the valuable help in the experiments performed using the fsTHz spectroscopy beamlines and 5A MS-XRS beamlines at the Pohang Light Source (PLS).

Publisher Copyright:
© 2019, The Author(s).

All Science Journal Classification (ASJC) codes

  • General


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