Partial oxidation of methane over nickel catalysts supported on various aluminas

Partial oxidation of methane (POM) was systematically investigated in a fixed bed reactor over 12 wt% Ni catalysts supported on α-Al ₂O₃, γ-A1₂O₃ and *θ-Al₂O₃ which were prepared at different conditions. Results indicate that the catalytic activity toward POM strongly depends on the BET surface area of the support. All the Ni/θ-Al ₂O₃ catalysts showed high activity toward POM due to the less formation of inactive NiA1₂O₄ species, the existence of NiO_x species and stable θ-Al₂O₃ phase. Although Ni/γ-Al₂O₃ showed the highest activity toward POM, long-time stability cannot be expected as a result of the deterioration of the support at higher temperature, which is revealed from BET results. From the reaction and characterization results, it is inferred that the optimal conditions for the preparation of θ-A1₂O₃ are 1,173 K and 12 h.