Oxidative fusion reactions of meso-(diarylamino)porphyrins

Norihito Fukui; Won Young Cha; Sangsu Lee; Sumito Tokuji; Dongho Kim; Hideki Yorimitsu; Atsuhiro Osuka

doi:10.1002/anie.201304794

Oxidative fusion reactions of meso-(diarylamino)porphyrins

Norihito Fukui, Won Young Cha, Sangsu Lee, Sumito Tokuji, Dongho Kim, Hideki Yorimitsu, Atsuhiro Osuka

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

79 Citations (Scopus)

Abstract

Creating cool fusion: The oxidative fusion of meso-(diarylamino)porphyrins depends heavily on the structures of the diarylamino groups. Bridged diarylamino groups result in the oxidative fusion of 3,5-di-tert-butylphenyl groups to the porphyrin moiety (blue), while non-bridged diarylamino groups invoke formation of nitrogen-embedded aminophenylene-fused porphyrins (red).

Original language	English
Pages (from-to)	9728-9732
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	52
Issue number	37
DOIs	https://doi.org/10.1002/anie.201304794
Publication status	Published - 2013 Sept 9

All Science Journal Classification (ASJC) codes

Catalysis
Chemistry(all)

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abstract = "Creating cool fusion: The oxidative fusion of meso-(diarylamino)porphyrins depends heavily on the structures of the diarylamino groups. Bridged diarylamino groups result in the oxidative fusion of 3,5-di-tert-butylphenyl groups to the porphyrin moiety (blue), while non-bridged diarylamino groups invoke formation of nitrogen-embedded aminophenylene-fused porphyrins (red).",

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AU - Tokuji, Sumito

AU - Kim, Dongho

AU - Yorimitsu, Hideki

AU - Osuka, Atsuhiro

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Oxidative fusion reactions of meso-(diarylamino)porphyrins

Abstract

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