On the mechanism of deoxygenation of secondary alcohols by tin hydride reduction of methyl xanthates and other thiocarbonyl derivatives

Derek H.R. Barton; Jang Doo Ok; Joseph Cs Jaszberenyi

doi:10.1016/S0040-4039(00)94480-0

On the mechanism of deoxygenation of secondary alcohols by tin hydride reduction of methyl xanthates and other thiocarbonyl derivatives

Derek H.R. Barton, Jang Doo Ok, Joseph Cs Jaszberenyi

Chemistry and Medical Chemistry

Research output: Contribution to journal › Article › peer-review

76 Citations (Scopus)

Abstract

The room temperature deoxygenation of xanthates and thionocarbonates using (n-Bu) ₃Sn-H - Et₃B - air has been studied, especially with ¹¹⁹Sn N.M.R. spectroscopy. The original conception of tin radical attack on thiocarbonyl is confirmed.

Original language	English
Pages (from-to)	3991-3994
Number of pages	4
Journal	Tetrahedron Letters
Volume	31
Issue number	28
DOIs	https://doi.org/10.1016/S0040-4039(00)94480-0
Publication status	Published - 1990

All Science Journal Classification (ASJC) codes

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/S0040-4039(00)94480-0

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title = "On the mechanism of deoxygenation of secondary alcohols by tin hydride reduction of methyl xanthates and other thiocarbonyl derivatives",

abstract = "The room temperature deoxygenation of xanthates and thionocarbonates using (n-Bu) 3Sn-H - Et3B - air has been studied, especially with 119Sn N.M.R. spectroscopy. The original conception of tin radical attack on thiocarbonyl is confirmed.",

author = "Barton, {Derek H.R.} and {Doo Ok}, Jang and Jaszberenyi, {Joseph Cs}",

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AU - Jaszberenyi, Joseph Cs

PY - 1990

Y1 - 1990

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AB - The room temperature deoxygenation of xanthates and thionocarbonates using (n-Bu) 3Sn-H - Et3B - air has been studied, especially with 119Sn N.M.R. spectroscopy. The original conception of tin radical attack on thiocarbonyl is confirmed.

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On the mechanism of deoxygenation of secondary alcohols by tin hydride reduction of methyl xanthates and other thiocarbonyl derivatives

Abstract

All Science Journal Classification (ASJC) codes

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