Novel Flexible Transparent Conductive Films with Enhanced Chemical and Electromechanical Sustainability: TiO₂ Nanosheet-Ag Nanowire Hybrid

Flexible transparent conductive films (TCFs) of TiO₂ nanosheet (TiO₂ NS) and silver nanowire (Ag NW) network hybrid were prepared through a simple and scalable solution-based process. The as-formed TiO₂ NS-Ag NW hybrid TCF shows a high optical transmittance (TT: 97% (90.2% including plastic substrate)) and low sheet resistance (R_s: 40 Ω/sq). In addition, the TiO₂ NS-Ag NW hybrid TCF exhibits a long-time chemical/aging and electromechanical stability. As for the chemical/aging stability, the hybrid TCF of Ag NW and TiO₂ NS reveals a retained initial conductivity (ΔR_s/R_s < 1%) under ambient oxidant gas over a month, superior to that of bare Ag NW (δR_s/R_s > 4000%) or RuO₂ NS-Ag NW hybrid (δR_s/R_s > 200%). As corroborated by the density functional theory simulation, the superb chemical stability of TiO₂ NS-Ag NW hybrid is attributable to the unique role of TiO₂ NS as a barrier, which prevents Ag NW's chemical corrosion via the attenuated adsorption of sulfidation molecules (H₂S) on TiO₂ NS. With respect to the electromechanical stability, in contrast to Ag NWs (δR/R₀ 152.9%), our hybrid TCF shows a limited increment of fractional resistivity (ΔR/R₀ - 14.4%) after 200 000 cycles of the 1R bending test (strain: 6.7%) owing to mechanically welded Ag NW networks by TiO₂ NS. Overall, our unique hybrid of TiO₂ NS and Ag NW exhibits excellent electrical/optical properties and reliable chemical/electromechanical stabilities.