Nonvolatile polymer memory with nanoconfinement of ferroelectric crystals

Seok Ju Kang, Insung Bae, Yu Jin Shin, Youn Jung Park, June Huh, Sang Min Park, Ho Cheol Kim, Cheolmin Park

Research output: Contribution to journalArticlepeer-review

115 Citations (Scopus)


We demonstrate significantly improved performance of a nonvolatile polymeric ferroelectric field effect transistor (FeFET) memory using nanoscopic confinement of poly(vinylidene fluoride-co-trifluoroethylene) (PVDF-TrFE) within self-assembled organosilicate (OS) lamellae. Periodic OS lamellae with 30 nm in width and 50 nm in periodicity were templated using block copolymer self-assembly. Confined crystallization of PVDF-TrFE not only significantly reduces gate leakage current but also facilitates ferroelectric polarization switching. These benefits are due to the elimination of structural defects and the development of an effective PVDF-TrFE crystal orientation through nanoconfinement. A bottom gate FeFET fabricated using a single-crystalline triisopropylsilylethynyl pentacene channel and PVDF-TrFE/OS hybrid gate insulator shows characteristic source-drain current hysteresis that is fully saturated at a programming voltage of ±8 V with an ON/OFF current ratio and a data retention time of approximately 102 and 2 h, respectively.

Original languageEnglish
Pages (from-to)138-144
Number of pages7
JournalNano letters
Issue number1
Publication statusPublished - 2011 Jan 12

All Science Journal Classification (ASJC) codes

  • Bioengineering
  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics
  • Mechanical Engineering


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