New Na-Ion Solid Electrolytes Na4−xSn1−xSbxS4 (0.02 ≤ x ≤ 0.33) for All-Solid-State Na-Ion Batteries

Jongwook W. Heo, Abhik Banerjee, Kern Ho Park, Yoon Seok Jung, Seung Tae Hong

Research output: Contribution to journalArticlepeer-review

90 Citations (Scopus)

Abstract

Sulfide Na-ion solid electrolytes (SEs) are key to enable room-temperature operable all-solid-state Na-ion batteries that are attractive for large-scale energy storage applications. To date, few sulfide Na-ion SEs have been developed and most of the SEs developed contain P and suffer from poor chemical stability. Herein, discovery of a new structural class of tetragonal Na4−xSn1−xSbxS4 (0.02 ≤ x ≤ 0.33) with space group I41/acd is described. The evolution of a new phase, distinctly different from Na4SnS4 or Na3SbS4, allows fast ionic conduction in 3D pathways (0.2–0.5 mS cm−1 at 30 °C). Moreover, their excellent air stability and reversible dissolution in water and precipitation are highlighted. Specifically, TiS2/Na–Sn all-solid-state Na-ion batteries using Na3.75Sn0.75Sb0.25S4 demonstrates high capacity (201 mA h (g of TiS2)−1) with excellent reversibility.

Original languageEnglish
Article number1702716
JournalAdvanced Energy Materials
Volume8
Issue number11
DOIs
Publication statusPublished - 2018 Apr 16

Bibliographical note

Publisher Copyright:
© 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim

All Science Journal Classification (ASJC) codes

  • Renewable Energy, Sustainability and the Environment
  • General Materials Science

Fingerprint

Dive into the research topics of 'New Na-Ion Solid Electrolytes Na4−xSn1−xSbxS4 (0.02 ≤ x ≤ 0.33) for All-Solid-State Na-Ion Batteries'. Together they form a unique fingerprint.

Cite this