Multi component self-assembly: Supramolecular organic frameworks containing metal-rotaxane subunits (RSOFs)

Han Yuan Gong; Brett M. Rambo; Cory A. Nelson; Won Cho; Vincent M. Lynch; Xiaoyang Zhu; Moonhyun Oh; Jonathan L. Sessler

doi:10.1039/c1dt11495f

Multi component self-assembly: Supramolecular organic frameworks containing metal-rotaxane subunits (RSOFs)

Han Yuan Gong, Brett M. Rambo, Cory A. Nelson, Won Cho, Vincent M. Lynch, Xiaoyang Zhu, Moonhyun Oh, Jonathan L. Sessler

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

27 Citations (Scopus)

Abstract

A facile, one-pot synthesis of rotaxanated supramolecular organic frameworks (RSOFs) is reported. These systems consist of bis-carboxylate anions threaded through the core of tetraimidazolium macrocycles. Trivalent metal cations, yttrium(iii) and smaller lanthanides, are used to "lock" the threaded strut in place. This results in the formation of three-dimensional RSOFs.

Original language	English
Pages (from-to)	1134-1137
Number of pages	4
Journal	Dalton Transactions
Volume	41
Issue number	4
DOIs	https://doi.org/10.1039/c1dt11495f
Publication status	Published - 2012 Jan 28

All Science Journal Classification (ASJC) codes

Inorganic Chemistry

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10.1039/c1dt11495f

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AU - Gong, Han Yuan

AU - Rambo, Brett M.

AU - Nelson, Cory A.

AU - Cho, Won

AU - Lynch, Vincent M.

AU - Zhu, Xiaoyang

AU - Oh, Moonhyun

AU - Sessler, Jonathan L.

PY - 2012/1/28

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N2 - A facile, one-pot synthesis of rotaxanated supramolecular organic frameworks (RSOFs) is reported. These systems consist of bis-carboxylate anions threaded through the core of tetraimidazolium macrocycles. Trivalent metal cations, yttrium(iii) and smaller lanthanides, are used to "lock" the threaded strut in place. This results in the formation of three-dimensional RSOFs.

AB - A facile, one-pot synthesis of rotaxanated supramolecular organic frameworks (RSOFs) is reported. These systems consist of bis-carboxylate anions threaded through the core of tetraimidazolium macrocycles. Trivalent metal cations, yttrium(iii) and smaller lanthanides, are used to "lock" the threaded strut in place. This results in the formation of three-dimensional RSOFs.

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Multi component self-assembly: Supramolecular organic frameworks containing metal-rotaxane subunits (RSOFs)

Abstract

All Science Journal Classification (ASJC) codes

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