TY - JOUR
T1 - Metal-catalysed alkyl ketone to ethyl ketone conversions in chelating ketones via carbon-carbon bond cleavage
AU - Suggs, J. William
AU - Jun, Chul Ho
PY - 1985
Y1 - 1985
N2 - 8-Quinolinyl alkyl ketones, in which the alkyl group has β-hydrogens, react with various Rh| and lr| complexes under ethylene to give, in a catalytic process, 8-quinolinyl ethyl ketone; the same reaction with 8-quinolinyl phenyl ketone produces styrene via ethylene insertion into a rhodium-phenyl bond and β-elimination of the resulting phenylethyl complex.
AB - 8-Quinolinyl alkyl ketones, in which the alkyl group has β-hydrogens, react with various Rh| and lr| complexes under ethylene to give, in a catalytic process, 8-quinolinyl ethyl ketone; the same reaction with 8-quinolinyl phenyl ketone produces styrene via ethylene insertion into a rhodium-phenyl bond and β-elimination of the resulting phenylethyl complex.
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U2 - 10.1039/C39850000092
DO - 10.1039/C39850000092
M3 - Article
AN - SCOPUS:0011500055
SN - 0022-4936
SP - 92
EP - 93
JO - Journal of the Chemical Society, Chemical Communications
JF - Journal of the Chemical Society, Chemical Communications
IS - 2
ER -