Mechanism and kinetics of the quantitative aminolysis reaction of poly(β-benzyl L-aspartate)(PBLA)

Masataka Nakanishi; Woo Dong Jang; Makoto Oba; Yuichi Yamasaki; Kazunori Kataoka

Mechanism and kinetics of the quantitative aminolysis reaction of poly(β-benzyl L-aspartate)(PBLA)

Masataka Nakanishi, Woo Dong Jang, Makoto Oba, Yuichi Yamasaki, Kazunori Kataoka

Department of Chemistry

Research output: Contribution to conference › Paper › peer-review

Abstract

The quantitative aminolysis reactions were successfully achieved by reacting PBLA with a variety of primary amines.The specific rotations of the poly(aspartamide) derivatives synthesized by this reaction depend on the initial condition of the hyper structure of PBLA in the solvents. The mechanism of this reaction may occur not just only through the ester-amide exchange on the side chain but also through the transformation involving α -methine and β -methylene, which also effect the specific rotation.

Original language	English
Pages	673
Number of pages	1
Publication status	Published - 2006
Event	55th SPSJ Annual Meeting - Nagoya, Japan Duration: 2006 May 24 → 2006 May 26

Other

Other	55th SPSJ Annual Meeting
Country/Territory	Japan
City	Nagoya
Period	06/5/24 → 06/5/26

All Science Journal Classification (ASJC) codes

Engineering(all)

Cite this

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title = "Mechanism and kinetics of the quantitative aminolysis reaction of poly(β-benzyl L-aspartate)(PBLA)",

abstract = "The quantitative aminolysis reactions were successfully achieved by reacting PBLA with a variety of primary amines.The specific rotations of the poly(aspartamide) derivatives synthesized by this reaction depend on the initial condition of the hyper structure of PBLA in the solvents. The mechanism of this reaction may occur not just only through the ester-amide exchange on the side chain but also through the transformation involving α -methine and β -methylene, which also effect the specific rotation.",

author = "Masataka Nakanishi and Jang, {Woo Dong} and Makoto Oba and Yuichi Yamasaki and Kazunori Kataoka",

year = "2006",

language = "English",

pages = "673",

note = "55th SPSJ Annual Meeting ; Conference date: 24-05-2006 Through 26-05-2006",

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TY - CONF

T1 - Mechanism and kinetics of the quantitative aminolysis reaction of poly(β-benzyl L-aspartate)(PBLA)

AU - Nakanishi, Masataka

AU - Jang, Woo Dong

AU - Oba, Makoto

AU - Yamasaki, Yuichi

AU - Kataoka, Kazunori

PY - 2006

Y1 - 2006

N2 - The quantitative aminolysis reactions were successfully achieved by reacting PBLA with a variety of primary amines.The specific rotations of the poly(aspartamide) derivatives synthesized by this reaction depend on the initial condition of the hyper structure of PBLA in the solvents. The mechanism of this reaction may occur not just only through the ester-amide exchange on the side chain but also through the transformation involving α -methine and β -methylene, which also effect the specific rotation.

AB - The quantitative aminolysis reactions were successfully achieved by reacting PBLA with a variety of primary amines.The specific rotations of the poly(aspartamide) derivatives synthesized by this reaction depend on the initial condition of the hyper structure of PBLA in the solvents. The mechanism of this reaction may occur not just only through the ester-amide exchange on the side chain but also through the transformation involving α -methine and β -methylene, which also effect the specific rotation.

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UR - http://www.scopus.com/inward/citedby.url?scp=33749674182&partnerID=8YFLogxK

M3 - Paper

AN - SCOPUS:33749674182

SP - 673

T2 - 55th SPSJ Annual Meeting

Y2 - 24 May 2006 through 26 May 2006

ER -

Mechanism and kinetics of the quantitative aminolysis reaction of poly(β-benzyl L-aspartate)(PBLA)

Abstract

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All Science Journal Classification (ASJC) codes

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