Manganese tricarbonyl transfer (MTT) reagents in the construction of novel organometallic systems

Moonhyun Oh; Jeffrey A. Reingold; Gene B. Carpenter; Dwight A. Sweigart

doi:10.1016/j.ccr.2003.12.002

Manganese tricarbonyl transfer (MTT) reagents in the construction of novel organometallic systems

Moonhyun Oh, Jeffrey A. Reingold, Gene B. Carpenter, Dwight A. Sweigart

Department of Chemistry

Research output: Contribution to journal › Review article › peer-review

50 Citations (Scopus)

Abstract

Naphthalene and related conjugated polycyclic arenes readily coordinate through one carbocyclic ring to Mn(CO)₃⁺. The resulting complexes, e.g., (η⁶-naphthalene)Mn(CO)₃⁺, function as very effective manganese tricarbonyl transfer (MTT) reagents, largely because of facile η⁶→η⁴ ring slippage. The MTT complexes can be used to synthesize a range of novel organometallic systems, including metal-carbonyl-capped metallocenes, and homo- and heteronuclear bimetallic naphthalene complexes. They are also the basis for the complexation and activation of benzothiophenes to desulfurization and of hydroquinones to deprotonation and self-assembly into supramolecular quinonoid coordination networks.

Original language	English
Pages (from-to)	561-569
Number of pages	9
Journal	Coordination Chemistry Reviews
Volume	248
Issue number	7-8
DOIs	https://doi.org/10.1016/j.ccr.2003.12.002
Publication status	Published - 2004 Apr

Bibliographical note

Funding Information:
Acknowledgment is gratefully made to the National Science Foundation and to the donors of the American Chemical Society Petroleum Research Fund for support of this research.

All Science Journal Classification (ASJC) codes

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/j.ccr.2003.12.002

Cite this

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title = "Manganese tricarbonyl transfer (MTT) reagents in the construction of novel organometallic systems",

abstract = "Naphthalene and related conjugated polycyclic arenes readily coordinate through one carbocyclic ring to Mn(CO)3+. The resulting complexes, e.g., (η6-naphthalene)Mn(CO)3+, function as very effective manganese tricarbonyl transfer (MTT) reagents, largely because of facile η6→η4 ring slippage. The MTT complexes can be used to synthesize a range of novel organometallic systems, including metal-carbonyl-capped metallocenes, and homo- and heteronuclear bimetallic naphthalene complexes. They are also the basis for the complexation and activation of benzothiophenes to desulfurization and of hydroquinones to deprotonation and self-assembly into supramolecular quinonoid coordination networks.",

author = "Moonhyun Oh and Reingold, {Jeffrey A.} and Carpenter, {Gene B.} and Sweigart, {Dwight A.}",

note = "Funding Information: Acknowledgment is gratefully made to the National Science Foundation and to the donors of the American Chemical Society Petroleum Research Fund for support of this research. ",

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journal = "Coordination Chemistry Reviews",

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AU - Oh, Moonhyun

AU - Reingold, Jeffrey A.

AU - Carpenter, Gene B.

AU - Sweigart, Dwight A.

N1 - Funding Information: Acknowledgment is gratefully made to the National Science Foundation and to the donors of the American Chemical Society Petroleum Research Fund for support of this research.

PY - 2004/4

Y1 - 2004/4

N2 - Naphthalene and related conjugated polycyclic arenes readily coordinate through one carbocyclic ring to Mn(CO)3+. The resulting complexes, e.g., (η6-naphthalene)Mn(CO)3+, function as very effective manganese tricarbonyl transfer (MTT) reagents, largely because of facile η6→η4 ring slippage. The MTT complexes can be used to synthesize a range of novel organometallic systems, including metal-carbonyl-capped metallocenes, and homo- and heteronuclear bimetallic naphthalene complexes. They are also the basis for the complexation and activation of benzothiophenes to desulfurization and of hydroquinones to deprotonation and self-assembly into supramolecular quinonoid coordination networks.

AB - Naphthalene and related conjugated polycyclic arenes readily coordinate through one carbocyclic ring to Mn(CO)3+. The resulting complexes, e.g., (η6-naphthalene)Mn(CO)3+, function as very effective manganese tricarbonyl transfer (MTT) reagents, largely because of facile η6→η4 ring slippage. The MTT complexes can be used to synthesize a range of novel organometallic systems, including metal-carbonyl-capped metallocenes, and homo- and heteronuclear bimetallic naphthalene complexes. They are also the basis for the complexation and activation of benzothiophenes to desulfurization and of hydroquinones to deprotonation and self-assembly into supramolecular quinonoid coordination networks.

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JO - Coordination Chemistry Reviews

JF - Coordination Chemistry Reviews

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Manganese tricarbonyl transfer (MTT) reagents in the construction of novel organometallic systems

Abstract

Bibliographical note

All Science Journal Classification (ASJC) codes

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