Long-term stability for Co-electrolysis of CO₂/steam assisted by catalyst-infiltrated solid oxide cells

This study investigated the long-term durability of catalyst(Pd or Fe)-infiltrated solid oxide cells for CO₂/steam co-electrolysis. Fuel-electrode supported solid oxide cells with dimensions of 5 × 5 cm² were fabricated, and palladium or iron was subsequently introduced via wet infiltration (as a form of PdO or FeO solution). The metallic catalysts were employed in the fuel-electrode to promote CO₂ reduction via reverse water gas shift reactions. The metal-precursor particles were well-dispersed on the fuel-electrode substrate, which formed a bimetallic alloy with Ni embedded on the substrate during high-temperature reduction processes. These planar cells were tested using a mixture of H₂O and CO₂ to measure the electrochemical and gas-production stabilities during 350 h of co-electrolysis operations. The results confirmed that compared to the Fe-infiltrated cell, the Pd-infiltrated cell had higher stabilities for both electrochemical reactions and gas-production given its resistance to carbon deposition.