Layered and two dimensional metal oxides for electrochemical energy conversion

Michelle P. Browne, Zdeněk Sofer, Martin Pumera

Research output: Contribution to journalReview articlepeer-review

255 Citations (Scopus)


The oxygen evolution and reduction reactions are two extremely important reactions in terms of energy applications. Currently, the Oxygen Evolution Reaction (OER) hinders the efficient running of electrolyzer devices which convert water into molecular H 2 . This H 2 can subsequently be used in a H 2 /O 2 fuel cell for the renewable generation of electricity with only H 2 O as a by-product. However, this fuel cell process is not economy feasible due to the sluggish kinetics of the Oxygen Reduction Reaction (ORR) at the device cathode, even with expensive state-of-the-art electrocatalytic materials. As of late, the amount of interest in the OER and ORR, from research laboratories from all over the globe, has risen rapidly in order to find cheap and efficient catalysts to replace the expensive platinum based catalysts currently used in the two aforementioned energy conversion/generation technologies. Layered transition metal oxides, based on the cheap transition metal oxides Mn, Co, Ni and Fe have been reported as viable catalysts for the OER and ORR. Layered structures have an added advantage over non-layered materials as the surface area can be increase by means of exfoliation, with potential for tailoring electrocatalytic activity. It has been shown that the fabrication process and post-synthetic treatments, e.g. anion exchange or exfoliation, of these materials can alter the catalytic activity of these materials. Here we summarise various fabrication methods and modifications utilised in literature to tailor the performance of layered transition metal and hydroxide based catalysts for the ORR and OER toward that of the state-of-the-art materials for these technologies.

Original languageEnglish
Pages (from-to)41-58
Number of pages18
JournalEnergy and Environmental Science
Issue number1
Publication statusPublished - 2019 Jan

Bibliographical note

Funding Information:
This work emanated from financial support from the Advanced Functional Nanorobots project (reg. no. CZ.02.1.01/0.0/0.0/ 15_003/0000444 financed by the EFRR). M. P. B. would also like to acknowledge the European Structural and Investment Funds, OP RDE-funded project ‘ChemJets’ (No. CZ.02.2.69/0.0/ 0.0/16_027/0008351). Z. S. was supported by Czech Science Foundation (GACR No. 17-11456S) and by the financial support of the Neuron Foundation for science support.

Publisher Copyright:
© 2019 The Royal Society of Chemistry.

All Science Journal Classification (ASJC) codes

  • Environmental Chemistry
  • Renewable Energy, Sustainability and the Environment
  • Nuclear Energy and Engineering
  • Pollution


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