Layer-by-layer assembled electrochromic film based on an alkylsulfonated polyaniline

Eunkyoung Kim; Yuna Kim

doi:10.1080/15421400500387361

Layer-by-layer assembled electrochromic film based on an alkylsulfonated polyaniline

Eunkyoung Kim, Yuna Kim

Department of Chemical and Biomolecular Engineering

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

An alkylsulfonated polyaniline, poly(aniline-N-butylsulfonate)s (PANBS), was assembled by the layer-by-layer (LBL) assembling technique as an electroactive anionic polymers for the layering. The counter ions for PANBS layer were polyaniline (H + doped) and vinylbenzyldimethyl-n-alkylammonium salts (VBAA) as the conductive and insulating polycation, respectively. High color contrast was observed when the electrochromic (EC) film was composed alternatively of the PANBS/PAN and PANBS/VBAA layer. Interlayer insulating gap controlled by the alkyl chain length of VBAA, was an important factor to increase EC response of the window assembled by the LBL method.

Original language	English
Pages (from-to)	173/[491]-179/[497]
Journal	Molecular Crystals and Liquid Crystals
Volume	447
DOIs	https://doi.org/10.1080/15421400500387361
Publication status	Published - 2006

Bibliographical note

Funding Information:
This work was financially supported by the Ministry of Science and Technology (MOST) of Korea and the grant from Yonsei University.

All Science Journal Classification (ASJC) codes

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

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title = "Layer-by-layer assembled electrochromic film based on an alkylsulfonated polyaniline",

abstract = "An alkylsulfonated polyaniline, poly(aniline-N-butylsulfonate)s (PANBS), was assembled by the layer-by-layer (LBL) assembling technique as an electroactive anionic polymers for the layering. The counter ions for PANBS layer were polyaniline (H + doped) and vinylbenzyldimethyl-n-alkylammonium salts (VBAA) as the conductive and insulating polycation, respectively. High color contrast was observed when the electrochromic (EC) film was composed alternatively of the PANBS/PAN and PANBS/VBAA layer. Interlayer insulating gap controlled by the alkyl chain length of VBAA, was an important factor to increase EC response of the window assembled by the LBL method.",

author = "Eunkyoung Kim and Yuna Kim",

note = "Funding Information: This work was financially supported by the Ministry of Science and Technology (MOST) of Korea and the grant from Yonsei University.",

year = "2006",

doi = "10.1080/15421400500387361",

language = "English",

volume = "447",

pages = "173/[491]--179/[497]",

journal = "Molecular Crystals and Liquid Crystals",

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T1 - Layer-by-layer assembled electrochromic film based on an alkylsulfonated polyaniline

AU - Kim, Eunkyoung

AU - Kim, Yuna

N1 - Funding Information: This work was financially supported by the Ministry of Science and Technology (MOST) of Korea and the grant from Yonsei University.

PY - 2006

Y1 - 2006

N2 - An alkylsulfonated polyaniline, poly(aniline-N-butylsulfonate)s (PANBS), was assembled by the layer-by-layer (LBL) assembling technique as an electroactive anionic polymers for the layering. The counter ions for PANBS layer were polyaniline (H + doped) and vinylbenzyldimethyl-n-alkylammonium salts (VBAA) as the conductive and insulating polycation, respectively. High color contrast was observed when the electrochromic (EC) film was composed alternatively of the PANBS/PAN and PANBS/VBAA layer. Interlayer insulating gap controlled by the alkyl chain length of VBAA, was an important factor to increase EC response of the window assembled by the LBL method.

AB - An alkylsulfonated polyaniline, poly(aniline-N-butylsulfonate)s (PANBS), was assembled by the layer-by-layer (LBL) assembling technique as an electroactive anionic polymers for the layering. The counter ions for PANBS layer were polyaniline (H + doped) and vinylbenzyldimethyl-n-alkylammonium salts (VBAA) as the conductive and insulating polycation, respectively. High color contrast was observed when the electrochromic (EC) film was composed alternatively of the PANBS/PAN and PANBS/VBAA layer. Interlayer insulating gap controlled by the alkyl chain length of VBAA, was an important factor to increase EC response of the window assembled by the LBL method.

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JO - Molecular Crystals and Liquid Crystals

JF - Molecular Crystals and Liquid Crystals

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Layer-by-layer assembled electrochromic film based on an alkylsulfonated polyaniline

Abstract

Bibliographical note

All Science Journal Classification (ASJC) codes

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