Large Two-Photon Absorption (TPA) cross-section of directly linked fused diporphyrins

Deok Yun Kim; Tae Kyu Ahn; Jung Ho Kwon; Dongho Kim; Takahisa Ikeue; Naoki Aratani; Atsuhiro Osuka; Motoyuki Shigeiwa; Shuichi Maeda

doi:10.1021/jp050747h

Large Two-Photon Absorption (TPA) cross-section of directly linked fused diporphyrins

Deok Yun Kim, Tae Kyu Ahn, Jung Ho Kwon, Dongho Kim, Takahisa Ikeue, Naoki Aratani, Atsuhiro Osuka, Motoyuki Shigeiwa, Shuichi Maeda

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

123 Citations (Scopus)

Abstract

The excited state dynamics and two-photon absorption properties of four novel triply linked porphyrin dimers in toluene have been investigated. The fused porphyrin dimers exhibit extremely increased two-photon absorption cross-section values (12 000-15 000 GM) compared with porphyrin monomers owing to much enhanced π-electron delocalization throughout the porphyrin dimer ring.

Original language	English
Pages (from-to)	2996-2999
Number of pages	4
Journal	Journal of Physical Chemistry A
Volume	109
Issue number	13
DOIs	https://doi.org/10.1021/jp050747h
Publication status	Published - 2005 Apr 7

All Science Journal Classification (ASJC) codes

Physical and Theoretical Chemistry

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10.1021/jp050747h

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abstract = "The excited state dynamics and two-photon absorption properties of four novel triply linked porphyrin dimers in toluene have been investigated. The fused porphyrin dimers exhibit extremely increased two-photon absorption cross-section values (12 000-15 000 GM) compared with porphyrin monomers owing to much enhanced π-electron delocalization throughout the porphyrin dimer ring.",

author = "Kim, {Deok Yun} and Ahn, {Tae Kyu} and Kwon, {Jung Ho} and Dongho Kim and Takahisa Ikeue and Naoki Aratani and Atsuhiro Osuka and Motoyuki Shigeiwa and Shuichi Maeda",

year = "2005",

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language = "English",

volume = "109",

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journal = "Journal of Physical Chemistry A",

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T1 - Large Two-Photon Absorption (TPA) cross-section of directly linked fused diporphyrins

AU - Kim, Deok Yun

AU - Ahn, Tae Kyu

AU - Kwon, Jung Ho

AU - Kim, Dongho

AU - Ikeue, Takahisa

AU - Aratani, Naoki

AU - Osuka, Atsuhiro

AU - Shigeiwa, Motoyuki

AU - Maeda, Shuichi

PY - 2005/4/7

Y1 - 2005/4/7

N2 - The excited state dynamics and two-photon absorption properties of four novel triply linked porphyrin dimers in toluene have been investigated. The fused porphyrin dimers exhibit extremely increased two-photon absorption cross-section values (12 000-15 000 GM) compared with porphyrin monomers owing to much enhanced π-electron delocalization throughout the porphyrin dimer ring.

AB - The excited state dynamics and two-photon absorption properties of four novel triply linked porphyrin dimers in toluene have been investigated. The fused porphyrin dimers exhibit extremely increased two-photon absorption cross-section values (12 000-15 000 GM) compared with porphyrin monomers owing to much enhanced π-electron delocalization throughout the porphyrin dimer ring.

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U2 - 10.1021/jp050747h

DO - 10.1021/jp050747h

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SP - 2996

EP - 2999

JO - Journal of Physical Chemistry A

JF - Journal of Physical Chemistry A

IS - 13

ER -

Large Two-Photon Absorption (TPA) cross-section of directly linked fused diporphyrins

Abstract

All Science Journal Classification (ASJC) codes

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