Kinetic separation of propene and propane in metal-organic frameworks: Controlling diffusion rates in plate-shaped crystals via tuning of pore apertures and crystallite aspect ratios

Chang Yeon Lee; Youn Sang Bae; Nak Cheon Jeong; Omar K. Farha; Amy A. Sarjeant; Charlotte L. Stern; Peter Nickias; Randall Q. Snurr; Joseph T. Hupp; Sonbinh T. Nguyen

doi:10.1021/ja200553m

Kinetic separation of propene and propane in metal-organic frameworks: Controlling diffusion rates in plate-shaped crystals via tuning of pore apertures and crystallite aspect ratios

Chang Yeon Lee, Youn Sang Bae, Nak Cheon Jeong, Omar K. Farha, Amy A. Sarjeant, Charlotte L. Stern, Peter Nickias, Randall Q. Snurr, Joseph T. Hupp, Sonbinh T. Nguyen

Department of Chemical and Biomolecular Engineering

Research output: Contribution to journal › Article › peer-review

225 Citations (Scopus)

Abstract

A series of isostructural, noncatenated, zinc-pillared-paddlewheel metal-organic framework materials has been synthesized from 1,2,4,5- tetrakis(carboxyphenyl)benzene and trans-1,2-dipyridylethene struts. Substantial kinetic selectivity in the adsorption of propene over propane can be observed, depending on the pore apertures and the rectangular-plate morphology of the crystals.(Figure Presented)

Original language	English
Pages (from-to)	5228-5231
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	133
Issue number	14
DOIs	https://doi.org/10.1021/ja200553m
Publication status	Published - 2011 Apr 13

All Science Journal Classification (ASJC) codes

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

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10.1021/ja200553m

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Lee, C. Y., Bae, Y. S., Jeong, N. C., Farha, O. K., Sarjeant, A. A., Stern, C. L., Nickias, P., Snurr, R. Q., Hupp, J. T., & Nguyen, S. T. (2011). Kinetic separation of propene and propane in metal-organic frameworks: Controlling diffusion rates in plate-shaped crystals via tuning of pore apertures and crystallite aspect ratios. Journal of the American Chemical Society, 133(14), 5228-5231. https://doi.org/10.1021/ja200553m

@article{def91f7044ad422e8e5f9a1dcb7f2629,

title = "Kinetic separation of propene and propane in metal-organic frameworks: Controlling diffusion rates in plate-shaped crystals via tuning of pore apertures and crystallite aspect ratios",

abstract = "A series of isostructural, noncatenated, zinc-pillared-paddlewheel metal-organic framework materials has been synthesized from 1,2,4,5- tetrakis(carboxyphenyl)benzene and trans-1,2-dipyridylethene struts. Substantial kinetic selectivity in the adsorption of propene over propane can be observed, depending on the pore apertures and the rectangular-plate morphology of the crystals.(Figure Presented)",

author = "Lee, {Chang Yeon} and Bae, {Youn Sang} and Jeong, {Nak Cheon} and Farha, {Omar K.} and Sarjeant, {Amy A.} and Stern, {Charlotte L.} and Peter Nickias and Snurr, {Randall Q.} and Hupp, {Joseph T.} and Nguyen, {Sonbinh T.}",

year = "2011",

month = apr,

day = "13",

doi = "10.1021/ja200553m",

language = "English",

volume = "133",

pages = "5228--5231",

journal = "Journal of the American Chemical Society",

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}

Lee, CY, Bae, YS, Jeong, NC, Farha, OK, Sarjeant, AA, Stern, CL, Nickias, P, Snurr, RQ, Hupp, JT & Nguyen, ST 2011, 'Kinetic separation of propene and propane in metal-organic frameworks: Controlling diffusion rates in plate-shaped crystals via tuning of pore apertures and crystallite aspect ratios', Journal of the American Chemical Society, vol. 133, no. 14, pp. 5228-5231. https://doi.org/10.1021/ja200553m

Kinetic separation of propene and propane in metal-organic frameworks: Controlling diffusion rates in plate-shaped crystals via tuning of pore apertures and crystallite aspect ratios. / Lee, Chang Yeon; Bae, Youn Sang; Jeong, Nak Cheon et al.
In: Journal of the American Chemical Society, Vol. 133, No. 14, 13.04.2011, p. 5228-5231.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Kinetic separation of propene and propane in metal-organic frameworks

T2 - Controlling diffusion rates in plate-shaped crystals via tuning of pore apertures and crystallite aspect ratios

AU - Lee, Chang Yeon

AU - Bae, Youn Sang

AU - Jeong, Nak Cheon

AU - Farha, Omar K.

AU - Sarjeant, Amy A.

AU - Stern, Charlotte L.

AU - Nickias, Peter

AU - Snurr, Randall Q.

AU - Hupp, Joseph T.

AU - Nguyen, Sonbinh T.

PY - 2011/4/13

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N2 - A series of isostructural, noncatenated, zinc-pillared-paddlewheel metal-organic framework materials has been synthesized from 1,2,4,5- tetrakis(carboxyphenyl)benzene and trans-1,2-dipyridylethene struts. Substantial kinetic selectivity in the adsorption of propene over propane can be observed, depending on the pore apertures and the rectangular-plate morphology of the crystals.(Figure Presented)

AB - A series of isostructural, noncatenated, zinc-pillared-paddlewheel metal-organic framework materials has been synthesized from 1,2,4,5- tetrakis(carboxyphenyl)benzene and trans-1,2-dipyridylethene struts. Substantial kinetic selectivity in the adsorption of propene over propane can be observed, depending on the pore apertures and the rectangular-plate morphology of the crystals.(Figure Presented)

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Kinetic separation of propene and propane in metal-organic frameworks: Controlling diffusion rates in plate-shaped crystals via tuning of pore apertures and crystallite aspect ratios

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