Jamming and unjamming transition of oil-in-water emulsions under continuous temperature change

To analyze the jamming and unjamming transition of oil-in-water emulsions under continuous temperature change, we simulated an emulsion system whose critical volume fraction was 0.3, which was validated with experimental results under oscillatory shear stress. In addition, we calculated the elastic modulus using the phase lag between strain and stress. Through heating and cooling, the emulsion experienced unjamming and jamming. A phenomenon-which is when the elastic modulus does not reach the expected value at the isothermal system-occurred when the emulsion system was cooled. We determined that this phenomenon was caused by the frequency being faster than the relaxation of the deformed droplets. We justified the relation between the frequency and relaxation by simulating the frequency dependency of the difference between the elastic modulus when cooled and the expected value at the same temperature.