Identifying the Correlation between Structural Parameters and Anisotropic Magnetic Properties in I-Mn-V Semiconductors: A Possible Room-Temperature Magnetism

Byung Il Yoo, Nahyun Lee, Bipin Lamichhane, Joonho Bang, Hyun Yong Song, Byung Cheol Park, Kyu Hyoung Lee, Seong Gon Kim, Sung Wng Kim

Research output: Contribution to journalArticlepeer-review

Abstract

Layer-structured materials are of central importance in a wide range of research fields owing to their unique properties originating from their two dimensionality and anisotropy. Herein, quasi-2D layer-structured I-Mn-V (I: alkali metals and V: pnictogen elements) compounds are investigated, which are potential antiferromagnetic (AFM) semiconductors. Single crystals of I-Mn-V compounds are successfully grown using the self-flux method and their electronic and magnetic properties are analyzed in correlation with structural parameters. Combined with theoretical calculations, the structural analysis indicates that the variation in the bonding angle between V-Mn-V is responsible for the change in the orbital hybridization of Mn and V, predominantly affecting their anisotropic semiconducting properties. Anisotropy in the magnetic properties is also found, where AFM ordering is expected to occur in the in-plane direction, as supported by spin–structure calculations. Furthermore, a possible ferromagnetic (FM) transition is discussed in relation to the vacancy defects. This study provides a candidate material group for AFM and FM spintronics and a basis for exploring magnetic semiconductors in quasi-2D layer-structured systems.

Original languageEnglish
Article number2200074
JournalAdvanced Materials
Volume34
Issue number33
DOIs
Publication statusPublished - 2022 Aug 18

Bibliographical note

Publisher Copyright:
© 2022 Wiley-VCH GmbH.

All Science Journal Classification (ASJC) codes

  • General Materials Science
  • Mechanics of Materials
  • Mechanical Engineering

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