Hydrogen isotope separation in metal-organic frameworks: Kinetic or chemical affinity quantum-sieving?

Ievgeniia Savchenko, Andreas Mavrandonakis, Thomas Heine, Hyunchul Oh, Julia Teufel, Michael Hirscher

Research output: Contribution to journalArticlepeer-review

34 Citations (Scopus)


Recently we reported hydrogen isotope separation by quantum sieving in metal-organic framework MFU-4, a framework exhibiting gates of about the same size as the molecular radii of D2 and H2. Due to its smaller effective particle size, D2 penetrates preferentially through the framework, resulting in remarkable selectivity. Surprisingly, MFU-4l, a material of very similar composition, but with substantially larger gate openings, shows appreciable hydrogen isotopologue selectivity. This selectivity occurs at low temperature and is smaller compared to earlier reported CPO-27, a framework exhibiting open metal sites. We show that this is caused by different adsorption enthalpies which are the result of quantum effects. It turns out that two independent hydrogen isotope separation mechanisms have been reported for MOFs: while kinetic quantum sieving works at cryogenic temperatures for materials with small pores, different adsorption energies allow chemical affinity quantum sieving. This effect is maximized by strong adsorption centers, which allow high selectivity at high temperatures (100 K and above), and is more appropriate for the rational design of isotope separation membranes.

Original languageEnglish
Pages (from-to)133-137
Number of pages5
JournalMicroporous and Mesoporous Materials
Publication statusPublished - 2015 Nov 1

Bibliographical note

Funding Information:
Financial Support of Deutsche Financial Support of Deutsche Forschungsgemeinschaft via the Priority Program “Metal-Organic Frameworks” (SPP 1362) is gratefully acknowledged.

Publisher Copyright:
© 2015

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics
  • Mechanics of Materials


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