Hybrid Silver Mesh Electrode for ITO-Free Flexible Polymer Solar Cells with Good Mechanical Stability

Wanjung Kim, Soyeon Kim, Iljoong Kang, Myung Sun Jung, Sung June Kim, Jung Kyu Kim, Sung Min Cho, Jung Hyun Kim, Jong Hyeok Park

Research output: Contribution to journalArticlepeer-review

36 Citations (Scopus)


Herein, we report a tailored Ag mesh electrode coated with poly(3,4-ethylenedioxythiophene) (PEDOT) polymer on a flexible polyethylene terephthalate (PET) substrate. The introduction of this highly conductive polymer solves the existing problems of Ag mesh-type transparent conductive electrodes, such as high pitch, roughness, current inhomogeneity, and adhesion problems between the Ag mesh grid and PEDOT polymer or PET substrate, to result in excellent electron spreading from the discrete Ag mesh onto the entire surface without sacrificing sheet conductivity and optical transparency. Based on this hybrid anode, we demonstrate highly efficient flexible polymer solar cells (PSCs) with a high fill factor of 67.11 %, which results in a power conversion efficiency (PCE) of 6.9 % based on a poly({4,8-bis[(2-ethylhexyl)oxy]benzo[1,2-b:4,5-b′] dithiophene-2,6-diyl}{3-fluoro-2-[(2-ethylhexyl) carbonyl]thieno[3,4-b]thiophenediyl}):[6,6]-phenyl-C71-butyric acid methyl ester bulk heterojunction device. Furthermore, the PSC device with the Ag mesh electrode also exhibits a good mechanical bending stability, as indicated by a 70 % retention of the initial PCE after 500 bending cycles compared with the PSC device with a PET/indium tin oxide electrode, which retained 0 % of the initial PCE after 300 bending cycles.

Original languageEnglish
Pages (from-to)1042-1049
Number of pages8
Issue number9
Publication statusPublished - 2016 May 10

Bibliographical note

Publisher Copyright:
© 2016 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

All Science Journal Classification (ASJC) codes

  • Environmental Chemistry
  • General Chemical Engineering
  • General Materials Science
  • General Energy


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