Highly electrochemiluminescent Ru(II) complexes containing 1,3-dihydro-1,1,3,3-tetramethyl-7,8-diazacyclopenta[1]phenanthren-2-one ligand

Do Nam Lee; Jung Hyo Min; Hak Mook Kim; Young Moo Jun; Han Nim Choi; Won Yong Lee; Byeong Hyo Kim

doi:10.1016/j.jorganchem.2004.11.048

Highly electrochemiluminescent Ru(II) complexes containing 1,3-dihydro-1,1,3,3-tetramethyl-7,8-diazacyclopenta[1]phenanthren-2-one ligand

Do Nam Lee, Jung Hyo Min, Hak Mook Kim, Young Moo Jun, Han Nim Choi, Won Yong Lee, Byeong Hyo Kim

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

A series of new ruthenium(II) complexes containing 1,3-dihydro-1,1,3,3- tetramethyl-7,8-diazacyclopenta[1]phenanthren-2-one (DTDP) ligand, such as [Ru(DTDP)_n(L)_3-n]²⁺ (L = 2,2′-bipyridyl (bpy), 4,4′-dimethyl-2,2′-bipyridyl (dmbpy), o-phenanthroline (o-phen), 5-chloro-o-phenanthroline (o-phen-Cl), 2,2′-bipyridine-4, 4′-dicarboxaldehyde (bpy-(CHO)₂), n = 1, 2, 3) were synthesized and examined as ECL materials. All the complexes were characterized in terms of electrochemical redox potential and relative ECL intensity, and were compared to the well-known tris(o-phenanthroline) ruthenium(II) complex. Most of the synthesized Ru(II) complexes containing the DTDP ligand exhibited more intense ECL emissions than [Ru(o-phen)₃]²⁺. In particular, the ECL intensities of [Ru(DTDP)(o-phen)₂]²⁺ and [Ru(DTDP)(bpy-(CHO)₂)₂]²⁺ were observed to be as high as 9-fold and 20-fold greater, respectively, than the ECL intensity of [Ru(o-phen)₃]²⁺.

Original language	English
Pages (from-to)	2002-2008
Number of pages	7
Journal	Journal of Organometallic Chemistry
Volume	690
Issue number	8 SPEC. ISS.
DOIs	https://doi.org/10.1016/j.jorganchem.2004.11.048
Publication status	Published - 2005 Apr 15

Bibliographical note

Funding Information:
Financial supports from the Korea Science and Engineering Foundation (R01-2000-00050 and CBMH), the RRC program of MOST/Gyeonggi-do, and Kwangwoon University in 2004 are greatly acknowledged.

All Science Journal Classification (ASJC) codes

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/j.jorganchem.2004.11.048

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@article{dd3c10fdde034a0d85c66c2ea1d383fb,

title = "Highly electrochemiluminescent Ru(II) complexes containing 1,3-dihydro-1,1,3,3-tetramethyl-7,8-diazacyclopenta[1]phenanthren-2-one ligand",

abstract = "A series of new ruthenium(II) complexes containing 1,3-dihydro-1,1,3,3- tetramethyl-7,8-diazacyclopenta[1]phenanthren-2-one (DTDP) ligand, such as [Ru(DTDP)n(L)3-n]2+ (L = 2,2′-bipyridyl (bpy), 4,4′-dimethyl-2,2′-bipyridyl (dmbpy), o-phenanthroline (o-phen), 5-chloro-o-phenanthroline (o-phen-Cl), 2,2′-bipyridine-4, 4′-dicarboxaldehyde (bpy-(CHO)2), n = 1, 2, 3) were synthesized and examined as ECL materials. All the complexes were characterized in terms of electrochemical redox potential and relative ECL intensity, and were compared to the well-known tris(o-phenanthroline) ruthenium(II) complex. Most of the synthesized Ru(II) complexes containing the DTDP ligand exhibited more intense ECL emissions than [Ru(o-phen)3]2+. In particular, the ECL intensities of [Ru(DTDP)(o-phen)2]2+ and [Ru(DTDP)(bpy-(CHO)2)2]2+ were observed to be as high as 9-fold and 20-fold greater, respectively, than the ECL intensity of [Ru(o-phen)3]2+.",

author = "Lee, {Do Nam} and Min, {Jung Hyo} and Kim, {Hak Mook} and Jun, {Young Moo} and Choi, {Han Nim} and Lee, {Won Yong} and Kim, {Byeong Hyo}",

note = "Funding Information: Financial supports from the Korea Science and Engineering Foundation (R01-2000-00050 and CBMH), the RRC program of MOST/Gyeonggi-do, and Kwangwoon University in 2004 are greatly acknowledged.",

year = "2005",

month = apr,

day = "15",

doi = "10.1016/j.jorganchem.2004.11.048",

language = "English",

volume = "690",

pages = "2002--2008",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier",

number = "8 SPEC. ISS.",

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TY - JOUR

T1 - Highly electrochemiluminescent Ru(II) complexes containing 1,3-dihydro-1,1,3,3-tetramethyl-7,8-diazacyclopenta[1]phenanthren-2-one ligand

AU - Lee, Do Nam

AU - Min, Jung Hyo

AU - Kim, Hak Mook

AU - Jun, Young Moo

AU - Choi, Han Nim

AU - Lee, Won Yong

AU - Kim, Byeong Hyo

N1 - Funding Information: Financial supports from the Korea Science and Engineering Foundation (R01-2000-00050 and CBMH), the RRC program of MOST/Gyeonggi-do, and Kwangwoon University in 2004 are greatly acknowledged.

PY - 2005/4/15

Y1 - 2005/4/15

N2 - A series of new ruthenium(II) complexes containing 1,3-dihydro-1,1,3,3- tetramethyl-7,8-diazacyclopenta[1]phenanthren-2-one (DTDP) ligand, such as [Ru(DTDP)n(L)3-n]2+ (L = 2,2′-bipyridyl (bpy), 4,4′-dimethyl-2,2′-bipyridyl (dmbpy), o-phenanthroline (o-phen), 5-chloro-o-phenanthroline (o-phen-Cl), 2,2′-bipyridine-4, 4′-dicarboxaldehyde (bpy-(CHO)2), n = 1, 2, 3) were synthesized and examined as ECL materials. All the complexes were characterized in terms of electrochemical redox potential and relative ECL intensity, and were compared to the well-known tris(o-phenanthroline) ruthenium(II) complex. Most of the synthesized Ru(II) complexes containing the DTDP ligand exhibited more intense ECL emissions than [Ru(o-phen)3]2+. In particular, the ECL intensities of [Ru(DTDP)(o-phen)2]2+ and [Ru(DTDP)(bpy-(CHO)2)2]2+ were observed to be as high as 9-fold and 20-fold greater, respectively, than the ECL intensity of [Ru(o-phen)3]2+.

AB - A series of new ruthenium(II) complexes containing 1,3-dihydro-1,1,3,3- tetramethyl-7,8-diazacyclopenta[1]phenanthren-2-one (DTDP) ligand, such as [Ru(DTDP)n(L)3-n]2+ (L = 2,2′-bipyridyl (bpy), 4,4′-dimethyl-2,2′-bipyridyl (dmbpy), o-phenanthroline (o-phen), 5-chloro-o-phenanthroline (o-phen-Cl), 2,2′-bipyridine-4, 4′-dicarboxaldehyde (bpy-(CHO)2), n = 1, 2, 3) were synthesized and examined as ECL materials. All the complexes were characterized in terms of electrochemical redox potential and relative ECL intensity, and were compared to the well-known tris(o-phenanthroline) ruthenium(II) complex. Most of the synthesized Ru(II) complexes containing the DTDP ligand exhibited more intense ECL emissions than [Ru(o-phen)3]2+. In particular, the ECL intensities of [Ru(DTDP)(o-phen)2]2+ and [Ru(DTDP)(bpy-(CHO)2)2]2+ were observed to be as high as 9-fold and 20-fold greater, respectively, than the ECL intensity of [Ru(o-phen)3]2+.

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U2 - 10.1016/j.jorganchem.2004.11.048

DO - 10.1016/j.jorganchem.2004.11.048

M3 - Article

AN - SCOPUS:16644382915

SN - 0022-328X

VL - 690

SP - 2002

EP - 2008

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 8 SPEC. ISS.

ER -

Highly electrochemiluminescent Ru(II) complexes containing 1,3-dihydro-1,1,3,3-tetramethyl-7,8-diazacyclopenta[1]phenanthren-2-one ligand

Abstract

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All Science Journal Classification (ASJC) codes

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