Highly active and stable Ni/Ce-ZrO2 catalyst for H2 production from methane

Hyun Seog Roh; Ki Won Jun; Wen Sheng Dong; Jong San Chang; Sang Eon Park; Yung Il Joe

doi:10.1016/S1381-1169(01)00358-2

Highly active and stable Ni/Ce-ZrO₂ catalyst for H₂ production from methane

Hyun Seog Roh, Ki Won Jun, Wen Sheng Dong, Jong San Chang, Sang Eon Park, Yung Il Joe

Division of Environmental Engineering

Research output: Contribution to journal › Article › peer-review

272 Citations (Scopus)

Abstract

Steam reforming of methane has been carried out aimed at the development of new and highly active catalysts for H₂ production. The catalytic properties of Ni catalysts supported on various supports have been investigated in connection with characterization results obtained from XRD, H₂ chemisorption, TPR and CO₂-TPD. Among the catalysts examined, Ni/Ce-ZrO₂ exhibited the best activity and stability. The remarkable catalytic performance is interpreted as a combined result of high oxygen storage capacity of ceria in Ce-ZrO₂, strong interaction between Ni and Ce-ZrO₂, basic property of the catalyst and rather high capability of H₂ uptake.

Original language	English
Pages (from-to)	137-142
Number of pages	6
Journal	Journal of Molecular Catalysis A: Chemical
Volume	181
Issue number	1-2
DOIs	https://doi.org/10.1016/S1381-1169(01)00358-2
Publication status	Published - 2002 Mar 25

All Science Journal Classification (ASJC) codes

Catalysis
Process Chemistry and Technology
Physical and Theoretical Chemistry

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10.1016/S1381-1169(01)00358-2

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title = "Highly active and stable Ni/Ce-ZrO2 catalyst for H2 production from methane",

abstract = "Steam reforming of methane has been carried out aimed at the development of new and highly active catalysts for H2 production. The catalytic properties of Ni catalysts supported on various supports have been investigated in connection with characterization results obtained from XRD, H2 chemisorption, TPR and CO2-TPD. Among the catalysts examined, Ni/Ce-ZrO2 exhibited the best activity and stability. The remarkable catalytic performance is interpreted as a combined result of high oxygen storage capacity of ceria in Ce-ZrO2, strong interaction between Ni and Ce-ZrO2, basic property of the catalyst and rather high capability of H2 uptake.",

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T1 - Highly active and stable Ni/Ce-ZrO2 catalyst for H2 production from methane

AU - Roh, Hyun Seog

AU - Jun, Ki Won

AU - Dong, Wen Sheng

AU - Chang, Jong San

AU - Park, Sang Eon

AU - Joe, Yung Il

PY - 2002/3/25

Y1 - 2002/3/25

N2 - Steam reforming of methane has been carried out aimed at the development of new and highly active catalysts for H2 production. The catalytic properties of Ni catalysts supported on various supports have been investigated in connection with characterization results obtained from XRD, H2 chemisorption, TPR and CO2-TPD. Among the catalysts examined, Ni/Ce-ZrO2 exhibited the best activity and stability. The remarkable catalytic performance is interpreted as a combined result of high oxygen storage capacity of ceria in Ce-ZrO2, strong interaction between Ni and Ce-ZrO2, basic property of the catalyst and rather high capability of H2 uptake.

AB - Steam reforming of methane has been carried out aimed at the development of new and highly active catalysts for H2 production. The catalytic properties of Ni catalysts supported on various supports have been investigated in connection with characterization results obtained from XRD, H2 chemisorption, TPR and CO2-TPD. Among the catalysts examined, Ni/Ce-ZrO2 exhibited the best activity and stability. The remarkable catalytic performance is interpreted as a combined result of high oxygen storage capacity of ceria in Ce-ZrO2, strong interaction between Ni and Ce-ZrO2, basic property of the catalyst and rather high capability of H2 uptake.

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Highly active and stable Ni/Ce-ZrO₂ catalyst for H₂ production from methane

Abstract

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