High propene/propane selectivity in isostructural metal-organic frameworks with high densities of open metal sites

Youn Sang Bae; Chang Yeon Lee; Ki Chul Kim; Omar K. Farha; Peter Nickias; Joseph T. Hupp; Sonbinh T. Nguyen; Randall Q. Snurr

doi:10.1002/anie.201107534

High propene/propane selectivity in isostructural metal-organic frameworks with high densities of open metal sites

Youn Sang Bae, Chang Yeon Lee, Ki Chul Kim, Omar K. Farha, Peter Nickias, Joseph T. Hupp, Sonbinh T. Nguyen, Randall Q. Snurr

Department of Chemical and Biomolecular Engineering

Research output: Contribution to journal › Article › peer-review

372 Citations (Scopus)

Abstract

Two go in, one comes out: A series of isostructural M-MOF-74 materials (M=Co, Mn, and Mg) with high densities of open metal sites have been examined for the selective adsorption of propene over propane. Co-MOF-74 exhibits the highest thermodynamic C ₃H ₆/C ₃H ₈ selectivity (ca. 45) reported for any MOF to date.

Original language	English
Pages (from-to)	1857-1860
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	51
Issue number	8
DOIs	https://doi.org/10.1002/anie.201107534
Publication status	Published - 2012 Feb 20

All Science Journal Classification (ASJC) codes

Catalysis
Chemistry(all)

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10.1002/anie.201107534

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abstract = "Two go in, one comes out: A series of isostructural M-MOF-74 materials (M=Co, Mn, and Mg) with high densities of open metal sites have been examined for the selective adsorption of propene over propane. Co-MOF-74 exhibits the highest thermodynamic C 3H 6/C 3H 8 selectivity (ca. 45) reported for any MOF to date.",

author = "Bae, {Youn Sang} and Lee, {Chang Yeon} and Kim, {Ki Chul} and Farha, {Omar K.} and Peter Nickias and Hupp, {Joseph T.} and Nguyen, {Sonbinh T.} and Snurr, {Randall Q.}",

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AU - Bae, Youn Sang

AU - Lee, Chang Yeon

AU - Kim, Ki Chul

AU - Farha, Omar K.

AU - Nickias, Peter

AU - Hupp, Joseph T.

AU - Nguyen, Sonbinh T.

AU - Snurr, Randall Q.

PY - 2012/2/20

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N2 - Two go in, one comes out: A series of isostructural M-MOF-74 materials (M=Co, Mn, and Mg) with high densities of open metal sites have been examined for the selective adsorption of propene over propane. Co-MOF-74 exhibits the highest thermodynamic C 3H 6/C 3H 8 selectivity (ca. 45) reported for any MOF to date.

AB - Two go in, one comes out: A series of isostructural M-MOF-74 materials (M=Co, Mn, and Mg) with high densities of open metal sites have been examined for the selective adsorption of propene over propane. Co-MOF-74 exhibits the highest thermodynamic C 3H 6/C 3H 8 selectivity (ca. 45) reported for any MOF to date.

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High propene/propane selectivity in isostructural metal-organic frameworks with high densities of open metal sites

Abstract

All Science Journal Classification (ASJC) codes

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