Hexaphyrin fused to two anthracenes

Koji Naoda, Hirotaka Mori, Naoki Aratani, Byung Sun Lee, Dongho Kim, Atsuhiro Osuka

Research output: Contribution to journalArticlepeer-review

28 Citations (Scopus)

Abstract

Gold standard: A bis(Au III) complex containing the title compound was prepared and characterized (see scheme; DDQ=2,3-dichloro-5,6- dicyano-1,4-benzoquinone, Tf=trifluoromethanesulfonyl). Owing to the effective conjugative network over the flat and elongated rectangular molecular frame, this complex displays a remarkably red-shifted and sharp Q-band-like band at 1467 nm, multiple reversible redox potentials, and a large TPA cross-section value.

Original languageEnglish
Pages (from-to)9856-9859
Number of pages4
JournalAngewandte Chemie - International Edition
Volume51
Issue number39
DOIs
Publication statusPublished - 2012 Sept 24

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

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