Helicity control of an indolocarbazole foldamer by chiral organic anions

Jae Min Suk; Dan A. Kim; Kyu Sung Jeong

doi:10.1021/ol3022148

Helicity control of an indolocarbazole foldamer by chiral organic anions

Jae Min Suk, Dan A. Kim, Kyu Sung Jeong

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

35 Citations (Scopus)

Abstract

Chiral organic anions such as camphorsulfonates and cAMP give rise to the preferential formation of a one-handed helix of an indolocarbazole foldamer, thus inducing characteristic circular dichroic (CD) signals. Moreover, the on and off switching of the chiroptical signal can be operated by acid and base chemistry which efficiently controls the association and dissipation of the foldamer and cAMP.

Original language	English
Pages (from-to)	5018-5021
Number of pages	4
Journal	Organic Letters
Volume	14
Issue number	19
DOIs	https://doi.org/10.1021/ol3022148
Publication status	Published - 2012 Oct 5

All Science Journal Classification (ASJC) codes

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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10.1021/ol3022148

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abstract = "Chiral organic anions such as camphorsulfonates and cAMP give rise to the preferential formation of a one-handed helix of an indolocarbazole foldamer, thus inducing characteristic circular dichroic (CD) signals. Moreover, the on and off switching of the chiroptical signal can be operated by acid and base chemistry which efficiently controls the association and dissipation of the foldamer and cAMP.",

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Helicity control of an indolocarbazole foldamer by chiral organic anions

Abstract

All Science Journal Classification (ASJC) codes

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