Greater Influence of Density on the Electrical Properties of an Organic Semiconductor Glass Compared to Molecular Orientation

Physical vapor deposition is widely used in the fabrication of organic light-emitting diodes and has the potential to adjust the density and orientation through substrate temperature control, which may lead to enhanced electrical performance. However, it is unclear whether this enhanced property is because of the horizontal molecular orientation or the increased density. The effects of the density and orientation on the electrical properties of a potential electron transport material, (3-dibenzo[c,h]acridin-7-yl)phenyl)diphenylphosphine oxide (TPPO-dibenzacridine), were investigated. According to the gyration tensor analysis, TPPO-dibenzacridine resembled an oblate ellipsoid. Furthermore, these films exhibited the highest density when prepared at a substrate temperature of 87.5% of the glass transition temperature with an increase in density of approximately 1.5%. Variable angle spectroscopic ellipsometry measurements confirmed that the transition dipole moment direction of the dibenzacridine moiety, which is involved in the electrical properties, remained isotropic at this temperature. Although horizontal orientations are known to optimize their π-π overlap and improve the electrical properties, the lowest driving voltage was observed under these conditions, which led to the conclusion that the enhanced electrical properties of TPPO-dibenzacridine are greatly influenced by the increased density rather than by the molecular orientation.