Generation of (dimethylaminomethyl)phenylvinylsilanone from 1,3-dihydroxy-1,3-disiloxane

Hyeon Mo Cho; Su Jung Lee; Myong Euy Lee

doi:10.1016/j.jorganchem.2012.02.002

Generation of (dimethylaminomethyl)phenylvinylsilanone from 1,3-dihydroxy-1,3-disiloxane

Hyeon Mo Cho, Su Jung Lee, Myong Euy Lee

University College

Research output: Contribution to journal › Article › peer-review

Abstract

Thermolysis of 1,3-dihydroxy-1,3-divinyldisiloxane, 1, having intramolecular donor atoms gave (dimethylaminomethyl)phenylvinylsilanone at moderated temperatures. The generated silanone underwent oligomerization to afford cyclic trisiloxane D3 and cyclic tetrasiloxane D4. The silanone species was identified by trapping experiments using hexamethylcyclotrisiloxane and MeOH. Interestingly, D3 and D4 were returned to 1 by hydrolysis.

Original language	English
Pages (from-to)	1-3
Number of pages	3
Journal	Journal of Organometallic Chemistry
Volume	706-707
DOIs	https://doi.org/10.1016/j.jorganchem.2012.02.002
Publication status	Published - 2012 Jun 1

Bibliographical note

Funding Information:
This research was supported by a grant from the Fundamental R&D Program for Core Technology of Materials funded by the Ministry of Knowledge Economy, Republic of Korea and was supported by WCU (World Class University) Program through the National Research Foundation of Korea funded by the Ministry of Education, Science and Technology ( R33-10082 ).

All Science Journal Classification (ASJC) codes

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

Access to Document

10.1016/j.jorganchem.2012.02.002

Cite this

@article{3c3831613f46427eb60d541efc1e8caa,

title = "Generation of (dimethylaminomethyl)phenylvinylsilanone from 1,3-dihydroxy-1,3-disiloxane",

abstract = "Thermolysis of 1,3-dihydroxy-1,3-divinyldisiloxane, 1, having intramolecular donor atoms gave (dimethylaminomethyl)phenylvinylsilanone at moderated temperatures. The generated silanone underwent oligomerization to afford cyclic trisiloxane D3 and cyclic tetrasiloxane D4. The silanone species was identified by trapping experiments using hexamethylcyclotrisiloxane and MeOH. Interestingly, D3 and D4 were returned to 1 by hydrolysis.",

author = "Cho, {Hyeon Mo} and Lee, {Su Jung} and Lee, {Myong Euy}",

note = "Funding Information: This research was supported by a grant from the Fundamental R&D Program for Core Technology of Materials funded by the Ministry of Knowledge Economy, Republic of Korea and was supported by WCU (World Class University) Program through the National Research Foundation of Korea funded by the Ministry of Education, Science and Technology ( R33-10082 ).",

year = "2012",

month = jun,

day = "1",

doi = "10.1016/j.jorganchem.2012.02.002",

language = "English",

volume = "706-707",

pages = "1--3",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier",

}

TY - JOUR

T1 - Generation of (dimethylaminomethyl)phenylvinylsilanone from 1,3-dihydroxy-1,3-disiloxane

AU - Cho, Hyeon Mo

AU - Lee, Su Jung

AU - Lee, Myong Euy

N1 - Funding Information: This research was supported by a grant from the Fundamental R&D Program for Core Technology of Materials funded by the Ministry of Knowledge Economy, Republic of Korea and was supported by WCU (World Class University) Program through the National Research Foundation of Korea funded by the Ministry of Education, Science and Technology ( R33-10082 ).

PY - 2012/6/1

Y1 - 2012/6/1

N2 - Thermolysis of 1,3-dihydroxy-1,3-divinyldisiloxane, 1, having intramolecular donor atoms gave (dimethylaminomethyl)phenylvinylsilanone at moderated temperatures. The generated silanone underwent oligomerization to afford cyclic trisiloxane D3 and cyclic tetrasiloxane D4. The silanone species was identified by trapping experiments using hexamethylcyclotrisiloxane and MeOH. Interestingly, D3 and D4 were returned to 1 by hydrolysis.

AB - Thermolysis of 1,3-dihydroxy-1,3-divinyldisiloxane, 1, having intramolecular donor atoms gave (dimethylaminomethyl)phenylvinylsilanone at moderated temperatures. The generated silanone underwent oligomerization to afford cyclic trisiloxane D3 and cyclic tetrasiloxane D4. The silanone species was identified by trapping experiments using hexamethylcyclotrisiloxane and MeOH. Interestingly, D3 and D4 were returned to 1 by hydrolysis.

UR - http://www.scopus.com/inward/record.url?scp=84862803834&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84862803834&partnerID=8YFLogxK

U2 - 10.1016/j.jorganchem.2012.02.002

DO - 10.1016/j.jorganchem.2012.02.002

M3 - Article

AN - SCOPUS:84862803834

SN - 0022-328X

VL - 706-707

SP - 1

EP - 3

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

ER -

Generation of (dimethylaminomethyl)phenylvinylsilanone from 1,3-dihydroxy-1,3-disiloxane

Abstract

Bibliographical note

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this