TY - JOUR
T1 - First example of the μ3-η1,η2,η1-C 60 bonding mode
T2 - Ligand-induced conversion of π to σ C60-metal complexes
AU - Song, Hyunjoon
AU - Lee, Kwangyeol
AU - Lee, Chang H.
AU - Park, Joon T.
AU - Chang, Hong Y.
AU - Choi, Moon Gun
PY - 2001/4/17
Y1 - 2001/4/17
N2 - A boat-shaped 1,4-cyclohexadiene-like ring is present in the C60 molecule with a novel σ-type μ3-η1,η2,η1 bonding mode in the clusters 2a and 2b. The change in coordination mode was induced by insertion of an RNC ligand into an Os-Os bond of the π-type C60 complex 1.R = CH2C6H5.
AB - A boat-shaped 1,4-cyclohexadiene-like ring is present in the C60 molecule with a novel σ-type μ3-η1,η2,η1 bonding mode in the clusters 2a and 2b. The change in coordination mode was induced by insertion of an RNC ligand into an Os-Os bond of the π-type C60 complex 1.R = CH2C6H5.
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U2 - 10.1002/1521-3773(20010417)40:8<1500::AID-ANIE1500>3.0.CO;2-W
DO - 10.1002/1521-3773(20010417)40:8<1500::AID-ANIE1500>3.0.CO;2-W
M3 - Article
AN - SCOPUS:0035901643
SN - 1433-7851
VL - 40
SP - 1500
EP - 1502
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
IS - 8
ER -