Facile isomerization of glucose into fructose using anion-exchange resins in organic solvents and application to direct conversion of glucose into furan compounds

Dasom Mun; Nhan Thanh Thien Huynh; Seunghan Shin; Yong Jin Kim; Sangyong Kim; Yong Gun Shul; Jin Ku Cho

doi:10.1007/s11164-017-2942-3

Facile isomerization of glucose into fructose using anion-exchange resins in organic solvents and application to direct conversion of glucose into furan compounds

Dasom Mun, Nhan Thanh Thien Huynh, Seunghan Shin, Yong Jin Kim, Sangyong Kim, Yong Gun Shul, Jin Ku Cho

Department of Chemical and Biomolecular Engineering

Research output: Contribution to journal › Article › peer-review

11 Citations (Scopus)

Abstract

The facile isomerization of glucose into fructose has been developed using commercially available anion-exchange resins (AERs) in organic solvents. Following extensive screening for the amount and type of AERs, solvents and reaction time, glucose was transformed into fructose in yields of up to 50% using Amberlite A-26 with macroreticular morphology and tertiary amine functionality in a protic solvent (ethanol). AERs could be used five times without a significant loss of activity. This isomerization method could be applied to the direct conversion of glucose into furan compounds by integrating the dehydration of fructose with cation-exchange resins.

Original language	English
Pages (from-to)	5495-5506
Number of pages	12
Journal	Research on Chemical Intermediates
Volume	43
Issue number	10
DOIs	https://doi.org/10.1007/s11164-017-2942-3
Publication status	Published - 2017 Oct 1

Bibliographical note

Funding Information:
We would like to acknowledge the financial support from the R&D Convergence Program of NST (National Research Council of Science and Technology) of the Republic of Korea and KITECH (Korea Institute of Industrial Technology) and from the Internal Research Program (PEO17250) of KITECH.

Publisher Copyright:
© 2017, Springer Science+Business Media Dordrecht.

All Science Journal Classification (ASJC) codes

Chemistry(all)

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10.1007/s11164-017-2942-3

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abstract = "The facile isomerization of glucose into fructose has been developed using commercially available anion-exchange resins (AERs) in organic solvents. Following extensive screening for the amount and type of AERs, solvents and reaction time, glucose was transformed into fructose in yields of up to 50% using Amberlite A-26 with macroreticular morphology and tertiary amine functionality in a protic solvent (ethanol). AERs could be used five times without a significant loss of activity. This isomerization method could be applied to the direct conversion of glucose into furan compounds by integrating the dehydration of fructose with cation-exchange resins.",

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Facile isomerization of glucose into fructose using anion-exchange resins in organic solvents and application to direct conversion of glucose into furan compounds. / Mun, Dasom; Huynh, Nhan Thanh Thien; Shin, Seunghan et al.
In: Research on Chemical Intermediates, Vol. 43, No. 10, 01.10.2017, p. 5495-5506.

Research output: Contribution to journal › Article › peer-review

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AU - Shin, Seunghan

AU - Kim, Yong Jin

AU - Kim, Sangyong

AU - Shul, Yong Gun

AU - Cho, Jin Ku

N1 - Funding Information: We would like to acknowledge the financial support from the R&D Convergence Program of NST (National Research Council of Science and Technology) of the Republic of Korea and KITECH (Korea Institute of Industrial Technology) and from the Internal Research Program (PEO17250) of KITECH. Publisher Copyright: © 2017, Springer Science+Business Media Dordrecht.

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N2 - The facile isomerization of glucose into fructose has been developed using commercially available anion-exchange resins (AERs) in organic solvents. Following extensive screening for the amount and type of AERs, solvents and reaction time, glucose was transformed into fructose in yields of up to 50% using Amberlite A-26 with macroreticular morphology and tertiary amine functionality in a protic solvent (ethanol). AERs could be used five times without a significant loss of activity. This isomerization method could be applied to the direct conversion of glucose into furan compounds by integrating the dehydration of fructose with cation-exchange resins.

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Facile isomerization of glucose into fructose using anion-exchange resins in organic solvents and application to direct conversion of glucose into furan compounds

Abstract

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