Enhancement of thermoelectric performance in a non-toxic CuInTe2/SnTe coated grain nanocomposite

Junphil Hwang, Minju Lee, Byung Kyu Yu, Mi Kyung Han, Woochul Kim, Jungwon Kim, Rabih Al Rahal Al Orabi, Hongchao Wang, Somnath Acharya, Jiyong Kim, Yingshi Jin, Hwanjoo Park, Sujin Kim, So Hyeon Yang, Sung Jin Kim

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12 Citations (Scopus)


A thermoelectric coated grain nanocomposite CuInTe2/SnTe with eco-friendly elements was synthesized. The nanocomposite contains a coating layer of CuInTe2and SnO2at the grain boundaries of the SnTe matrix. The coating layer was synthesized using the cation exchange process considering the hard soft acid base (HSAB) concept, the solubility product, and crystal structure. The CuInTe2coating layer blocks the low energy carriers of the composite resulting in 40% enhancement of the Seebeck coefficient due to energy filtering. The coherent phonon scattering by the coating layer of CuInTe2effectively reduces the lattice thermal conductivity to almost the minimum theoretical limit. The thermoelectric figure of merit (zT) for the CuInTe2/SnTe nanocomposite was as high as 1.68 at 823 K, which is significantly higher than that of bulk SnTe in the mid-temperature range. The averagezTfrom 373 K to 823 K for the nanocomposite was 0.76, which is promising for utilization in industrial application.

Original languageEnglish
Pages (from-to)14851-14858
Number of pages8
JournalJournal of Materials Chemistry A
Issue number26
Publication statusPublished - 2021 Jul 14

Bibliographical note

Publisher Copyright:
© The Royal Society of Chemistry 2021.

All Science Journal Classification (ASJC) codes

  • General Chemistry
  • Renewable Energy, Sustainability and the Environment
  • General Materials Science


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