TY - JOUR
T1 - Enhancement of chemical stability and crystallinity in porphyrin-containing covalent organic frameworks by intramolecular hydrogen bonds
AU - Kandambeth, Sharath
AU - Shinde, Digambar Balaji
AU - Panda, Manas K.
AU - Lukose, Binit
AU - Heine, Thomas
AU - Banerjee, Rahul
PY - 2013/12/2
Y1 - 2013/12/2
N2 - A strong bond: A strategy based on intramolecular hydrogen-binding interactions in 2D covalent organic frameworks (COFs) is shown to improve the crystallinity, porosity, and chemical stability of the material (see picture). The concept is validated by removing the hydrogen-bonding interaction in the methoxy analog which showed a lower stability and crystallinity.
AB - A strong bond: A strategy based on intramolecular hydrogen-binding interactions in 2D covalent organic frameworks (COFs) is shown to improve the crystallinity, porosity, and chemical stability of the material (see picture). The concept is validated by removing the hydrogen-bonding interaction in the methoxy analog which showed a lower stability and crystallinity.
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U2 - 10.1002/anie.201306775
DO - 10.1002/anie.201306775
M3 - Article
C2 - 24127339
AN - SCOPUS:84888589724
SN - 1433-7851
VL - 52
SP - 13052
EP - 13056
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
IS - 49
ER -