TY - JOUR
T1 - Electrochemical synthesis of a thiophene-containing cyclo[9]pyrrole
AU - Bui, Thanh Tuan
AU - Iordache, Adriana
AU - Chen, Zhongrui
AU - Roznyatovskiy, Vladimir V.
AU - Saint-Aman, Eric
AU - Lim, Jong Min
AU - Lee, Byung Sun
AU - Ghosh, Sudip
AU - Moutet, Jean Claude
AU - Sessler, Jonathan L.
AU - Kim, Dongho
AU - Bucher, Christophe
PY - 2012/5/7
Y1 - 2012/5/7
N2 - A new member of the cyclo[n]pyrrole class of expanded porphyrins could be prepared from the corresponding thiophene-containing terpyrrole precursor through use of a mild electrochemical oxidative procedure. The isolated macrocycle, featuring nine heterocyclic subunits directly connected through their α,α'-positions, is the largest cyclo[n]pyrrole derivative reported to date (see figure).
AB - A new member of the cyclo[n]pyrrole class of expanded porphyrins could be prepared from the corresponding thiophene-containing terpyrrole precursor through use of a mild electrochemical oxidative procedure. The isolated macrocycle, featuring nine heterocyclic subunits directly connected through their α,α'-positions, is the largest cyclo[n]pyrrole derivative reported to date (see figure).
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U2 - 10.1002/chem.201200196
DO - 10.1002/chem.201200196
M3 - Article
C2 - 22461174
AN - SCOPUS:84860703722
SN - 0947-6539
VL - 18
SP - 5853
EP - 5859
JO - Chemistry - A European Journal
JF - Chemistry - A European Journal
IS - 19
ER -