Electrochemical characterization of layered LiCoO2 films prepared by electrostatic spray deposition

Won Sub Yoon; Sung Ho Ban; Kyung Keun Lee; Kwang Bum Kim; Min Gyu Kim; Jay Min Lee

doi:10.1016/S0378-7753(01)00514-6

Electrochemical characterization of layered LiCoO₂ films prepared by electrostatic spray deposition

Won Sub Yoon, Sung Ho Ban, Kyung Keun Lee, Kwang Bum Kim, Min Gyu Kim, Jay Min Lee

Department of Materials Science and Engineering

Research output: Contribution to journal › Conference article › peer-review

57 Citations (Scopus)

Abstract

LiCoO₂ thin-film cathode was deposited on Pt-coated alumina substrate by the electrostatic spray deposition method. The average film weight of LiCoO₂ increased linearly with the deposition time. Electrochemical characterization was carried out by cyclic voltammetry and charge/discharge tests. These tests revealed that single phase HT-LiCoO₂ films could be obtained by the ESD method at temperature as low as 600°C and the LiCoO₂ film deposited by the ESD method showed very stable cycling characteristics. The crystallinity of the LiCoO₂ layers increased with increasing annealing temperature. XANES results showed that the LiCoO₂ film deposited by the ESD method does not show any changes of the local geometry and electronic structure around Co atoms after electrochemical cycling.

Original language	English
Pages (from-to)	282-286
Number of pages	5
Journal	Journal of Power Sources
Volume	97-98
DOIs	https://doi.org/10.1016/S0378-7753(01)00514-6
Publication status	Published - 2001 Jul
Event	10th International Meeting on Lithium Batteries - Como, Italy Duration: 2001 May 28 → 2001 Jun 2

All Science Journal Classification (ASJC) codes

Renewable Energy, Sustainability and the Environment
Energy Engineering and Power Technology
Physical and Theoretical Chemistry
Electrical and Electronic Engineering

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

Access to Document

10.1016/S0378-7753(01)00514-6

Cite this

@article{13f0e5e774c2457e9bd36beb1af0589e,

title = "Electrochemical characterization of layered LiCoO2 films prepared by electrostatic spray deposition",

abstract = "LiCoO2 thin-film cathode was deposited on Pt-coated alumina substrate by the electrostatic spray deposition method. The average film weight of LiCoO2 increased linearly with the deposition time. Electrochemical characterization was carried out by cyclic voltammetry and charge/discharge tests. These tests revealed that single phase HT-LiCoO2 films could be obtained by the ESD method at temperature as low as 600°C and the LiCoO2 film deposited by the ESD method showed very stable cycling characteristics. The crystallinity of the LiCoO2 layers increased with increasing annealing temperature. XANES results showed that the LiCoO2 film deposited by the ESD method does not show any changes of the local geometry and electronic structure around Co atoms after electrochemical cycling.",

author = "Yoon, {Won Sub} and Ban, {Sung Ho} and Lee, {Kyung Keun} and Kim, {Kwang Bum} and Kim, {Min Gyu} and Lee, {Jay Min}",

year = "2001",

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doi = "10.1016/S0378-7753(01)00514-6",

language = "English",

volume = "97-98",

pages = "282--286",

journal = "Journal of Power Sources",

issn = "0378-7753",

publisher = "Elsevier",

note = "10th International Meeting on Lithium Batteries ; Conference date: 28-05-2001 Through 02-06-2001",

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TY - JOUR

T1 - Electrochemical characterization of layered LiCoO2 films prepared by electrostatic spray deposition

AU - Yoon, Won Sub

AU - Ban, Sung Ho

AU - Lee, Kyung Keun

AU - Kim, Kwang Bum

AU - Kim, Min Gyu

AU - Lee, Jay Min

PY - 2001/7

Y1 - 2001/7

N2 - LiCoO2 thin-film cathode was deposited on Pt-coated alumina substrate by the electrostatic spray deposition method. The average film weight of LiCoO2 increased linearly with the deposition time. Electrochemical characterization was carried out by cyclic voltammetry and charge/discharge tests. These tests revealed that single phase HT-LiCoO2 films could be obtained by the ESD method at temperature as low as 600°C and the LiCoO2 film deposited by the ESD method showed very stable cycling characteristics. The crystallinity of the LiCoO2 layers increased with increasing annealing temperature. XANES results showed that the LiCoO2 film deposited by the ESD method does not show any changes of the local geometry and electronic structure around Co atoms after electrochemical cycling.

AB - LiCoO2 thin-film cathode was deposited on Pt-coated alumina substrate by the electrostatic spray deposition method. The average film weight of LiCoO2 increased linearly with the deposition time. Electrochemical characterization was carried out by cyclic voltammetry and charge/discharge tests. These tests revealed that single phase HT-LiCoO2 films could be obtained by the ESD method at temperature as low as 600°C and the LiCoO2 film deposited by the ESD method showed very stable cycling characteristics. The crystallinity of the LiCoO2 layers increased with increasing annealing temperature. XANES results showed that the LiCoO2 film deposited by the ESD method does not show any changes of the local geometry and electronic structure around Co atoms after electrochemical cycling.

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