Effect of ionic liquids on the conformation of a porphyrin-based viscometer

Laramie P. Jameson; Joseph D. Kimball; Zygmunt Gryczynski; Milan Balaz; Sergei V. Dzyuba

doi:10.1039/c3ra43001d

Effect of ionic liquids on the conformation of a porphyrin-based viscometer

Laramie P. Jameson, Joseph D. Kimball, Zygmunt Gryczynski, Milan Balaz, Sergei V. Dzyuba

Integrated Sciences and Engineering Division

Research output: Contribution to journal › Article › peer-review

22 Citations (Scopus)

Abstract

Structure of the cationic and anionic counterparts of ionic liquids has a significant impact on the conformational bias of the porphyrin rotor; an apparent correlation between the conformation and the viscosity of ionic liquids was noted, albeit it was found to be distinct and more complex from that found in molecular solvents.

Original language	English
Pages (from-to)	18300-18304
Number of pages	5
Journal	RSC Advances
Volume	3
Issue number	40
DOIs	https://doi.org/10.1039/c3ra43001d
Publication status	Published - 2013 Oct 28

All Science Journal Classification (ASJC) codes

Chemistry(all)
Chemical Engineering(all)

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title = "Effect of ionic liquids on the conformation of a porphyrin-based viscometer",

abstract = "Structure of the cationic and anionic counterparts of ionic liquids has a significant impact on the conformational bias of the porphyrin rotor; an apparent correlation between the conformation and the viscosity of ionic liquids was noted, albeit it was found to be distinct and more complex from that found in molecular solvents.",

author = "Jameson, {Laramie P.} and Kimball, {Joseph D.} and Zygmunt Gryczynski and Milan Balaz and Dzyuba, {Sergei V.}",

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AU - Jameson, Laramie P.

AU - Kimball, Joseph D.

AU - Gryczynski, Zygmunt

AU - Balaz, Milan

AU - Dzyuba, Sergei V.

PY - 2013/10/28

Y1 - 2013/10/28

N2 - Structure of the cationic and anionic counterparts of ionic liquids has a significant impact on the conformational bias of the porphyrin rotor; an apparent correlation between the conformation and the viscosity of ionic liquids was noted, albeit it was found to be distinct and more complex from that found in molecular solvents.

AB - Structure of the cationic and anionic counterparts of ionic liquids has a significant impact on the conformational bias of the porphyrin rotor; an apparent correlation between the conformation and the viscosity of ionic liquids was noted, albeit it was found to be distinct and more complex from that found in molecular solvents.

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JO - RSC Advances

JF - RSC Advances

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Effect of ionic liquids on the conformation of a porphyrin-based viscometer

Abstract

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