Dual functionalities of hydrogen-bonding self-assembled catalysts in chelation-assisted hydroacylation

Jung Woo Park; Ji Hye Park; Chul Ho Jun

doi:10.1021/jo800862q

Dual functionalities of hydrogen-bonding self-assembled catalysts in chelation-assisted hydroacylation

Jung Woo Park, Ji Hye Park, Chul Ho Jun

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

23 Citations (Scopus)

Abstract

(Figure Presented) A recyclable catalyst for chelation-assisted hydroacylation of an olefin with primary alcohol was developed using hydrogen-bonding self-assembled catalysts consisting of 2,6-diaminopyridine and barbiturate phosphine - rhodium(I) complex. Upon heating, these two catalysts act as homogeneous catalysts due to cleavage of the hydrogen bond, and these associate to form supramolecular assemblies via hydrogen bonding that can be separated from immiscible product phase upon cooling after the reaction.

Original language	English
Pages (from-to)	5598-5601
Number of pages	4
Journal	Journal of Organic Chemistry
Volume	73
Issue number	14
DOIs	https://doi.org/10.1021/jo800862q
Publication status	Published - 2008 Jul 18

All Science Journal Classification (ASJC) codes

Organic Chemistry

Access to Document

10.1021/jo800862q

Cite this

@article{ba87a97157244b71992518e263d7554b,

title = "Dual functionalities of hydrogen-bonding self-assembled catalysts in chelation-assisted hydroacylation",

abstract = "(Figure Presented) A recyclable catalyst for chelation-assisted hydroacylation of an olefin with primary alcohol was developed using hydrogen-bonding self-assembled catalysts consisting of 2,6-diaminopyridine and barbiturate phosphine - rhodium(I) complex. Upon heating, these two catalysts act as homogeneous catalysts due to cleavage of the hydrogen bond, and these associate to form supramolecular assemblies via hydrogen bonding that can be separated from immiscible product phase upon cooling after the reaction.",

author = "Park, {Jung Woo} and Park, {Ji Hye} and Jun, {Chul Ho}",

year = "2008",

month = jul,

day = "18",

doi = "10.1021/jo800862q",

language = "English",

volume = "73",

pages = "5598--5601",

journal = "Journal of Organic Chemistry",

issn = "0022-3263",

publisher = "American Chemical Society",

number = "14",

}

TY - JOUR

T1 - Dual functionalities of hydrogen-bonding self-assembled catalysts in chelation-assisted hydroacylation

AU - Park, Jung Woo

AU - Park, Ji Hye

AU - Jun, Chul Ho

PY - 2008/7/18

Y1 - 2008/7/18

N2 - (Figure Presented) A recyclable catalyst for chelation-assisted hydroacylation of an olefin with primary alcohol was developed using hydrogen-bonding self-assembled catalysts consisting of 2,6-diaminopyridine and barbiturate phosphine - rhodium(I) complex. Upon heating, these two catalysts act as homogeneous catalysts due to cleavage of the hydrogen bond, and these associate to form supramolecular assemblies via hydrogen bonding that can be separated from immiscible product phase upon cooling after the reaction.

AB - (Figure Presented) A recyclable catalyst for chelation-assisted hydroacylation of an olefin with primary alcohol was developed using hydrogen-bonding self-assembled catalysts consisting of 2,6-diaminopyridine and barbiturate phosphine - rhodium(I) complex. Upon heating, these two catalysts act as homogeneous catalysts due to cleavage of the hydrogen bond, and these associate to form supramolecular assemblies via hydrogen bonding that can be separated from immiscible product phase upon cooling after the reaction.

UR - http://www.scopus.com/inward/record.url?scp=48249084529&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=48249084529&partnerID=8YFLogxK

U2 - 10.1021/jo800862q

DO - 10.1021/jo800862q

M3 - Article

C2 - 18570474

AN - SCOPUS:48249084529

SN - 0022-3263

VL - 73

SP - 5598

EP - 5601

JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

IS - 14

ER -

Dual functionalities of hydrogen-bonding self-assembled catalysts in chelation-assisted hydroacylation

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this