Directly Pd(II)-bridged porphyrin belts with remarkable curvatures

Jianxin Song; Naoki Aratani; Ji Haeng Heo; Dongho Kim; Hiroshi Shinokubo; Atsuhiro Osuka

doi:10.1021/ja1046654

Directly Pd(II)-bridged porphyrin belts with remarkable curvatures

Jianxin Song, Naoki Aratani, Ji Haeng Heo, Dongho Kim, Hiroshi Shinokubo, Atsuhiro Osuka

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

50 Citations (Scopus)

Abstract

A β,β′-doubly 2,6-pyridylene-bridged porphyrin dimer and trimer were prepared by Suzuki-Miyaura coupling reactions and confirmed to have largely bent structures. These oligoporphyrins were readily metalated via meso-C-H bond activation with the assistance of the pyridyl nitrogen atoms to produce the corresponding Pd(II) complexes, which display even larger bent structures and larger TPA values at 800 nm.

Original language	English
Pages (from-to)	11868-11869
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	132
Issue number	34
DOIs	https://doi.org/10.1021/ja1046654
Publication status	Published - 2010 Sept 1

All Science Journal Classification (ASJC) codes

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

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10.1021/ja1046654

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abstract = "A β,β′-doubly 2,6-pyridylene-bridged porphyrin dimer and trimer were prepared by Suzuki-Miyaura coupling reactions and confirmed to have largely bent structures. These oligoporphyrins were readily metalated via meso-C-H bond activation with the assistance of the pyridyl nitrogen atoms to produce the corresponding Pd(II) complexes, which display even larger bent structures and larger TPA values at 800 nm.",

author = "Jianxin Song and Naoki Aratani and Heo, {Ji Haeng} and Dongho Kim and Hiroshi Shinokubo and Atsuhiro Osuka",

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AU - Song, Jianxin

AU - Aratani, Naoki

AU - Heo, Ji Haeng

AU - Kim, Dongho

AU - Shinokubo, Hiroshi

AU - Osuka, Atsuhiro

PY - 2010/9/1

Y1 - 2010/9/1

N2 - A β,β′-doubly 2,6-pyridylene-bridged porphyrin dimer and trimer were prepared by Suzuki-Miyaura coupling reactions and confirmed to have largely bent structures. These oligoporphyrins were readily metalated via meso-C-H bond activation with the assistance of the pyridyl nitrogen atoms to produce the corresponding Pd(II) complexes, which display even larger bent structures and larger TPA values at 800 nm.

AB - A β,β′-doubly 2,6-pyridylene-bridged porphyrin dimer and trimer were prepared by Suzuki-Miyaura coupling reactions and confirmed to have largely bent structures. These oligoporphyrins were readily metalated via meso-C-H bond activation with the assistance of the pyridyl nitrogen atoms to produce the corresponding Pd(II) complexes, which display even larger bent structures and larger TPA values at 800 nm.

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JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

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ER -

Directly Pd(II)-bridged porphyrin belts with remarkable curvatures

Abstract

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