Diphenylphosphine oxide: An alternative to organotin hydrides in the radical deoxygenation of alcohols

Doo Ok Jang; Dae Hyan Cho; Joonggon Kim

doi:10.1080/00397919808004902

Diphenylphosphine oxide: An alternative to organotin hydrides in the radical deoxygenation of alcohols

Doo Ok Jang, Dae Hyan Cho, Joonggon Kim

Chemistry and Medical Chemistry

Research output: Contribution to journal › Article › peer-review

17 Citations (Scopus)

Abstract

Various S-methyl dithiocarbonates of tertiary and secondary alcohols are effectively deoxygenated in high isolated yields by treatment with diphenylphosphine oxide and various radical initiators in boiling dioxane. Deoxygenation of S-methyl dithiocarbonate of primary alcohols can be accomplished similarly in boiling xylenes.

Original language	English
Pages (from-to)	3559-3565
Number of pages	7
Journal	Synthetic Communications
Volume	28
Issue number	19
DOIs	https://doi.org/10.1080/00397919808004902
Publication status	Published - 1998

All Science Journal Classification (ASJC) codes

Organic Chemistry

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10.1080/00397919808004902

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title = "Diphenylphosphine oxide: An alternative to organotin hydrides in the radical deoxygenation of alcohols",

abstract = "Various S-methyl dithiocarbonates of tertiary and secondary alcohols are effectively deoxygenated in high isolated yields by treatment with diphenylphosphine oxide and various radical initiators in boiling dioxane. Deoxygenation of S-methyl dithiocarbonate of primary alcohols can be accomplished similarly in boiling xylenes.",

author = "Jang, {Doo Ok} and Cho, {Dae Hyan} and Joonggon Kim",

year = "1998",

doi = "10.1080/00397919808004902",

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volume = "28",

pages = "3559--3565",

journal = "Synthetic Communications",

issn = "0039-7911",

publisher = "Taylor and Francis Ltd.",

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T2 - An alternative to organotin hydrides in the radical deoxygenation of alcohols

AU - Jang, Doo Ok

AU - Cho, Dae Hyan

AU - Kim, Joonggon

PY - 1998

Y1 - 1998

N2 - Various S-methyl dithiocarbonates of tertiary and secondary alcohols are effectively deoxygenated in high isolated yields by treatment with diphenylphosphine oxide and various radical initiators in boiling dioxane. Deoxygenation of S-methyl dithiocarbonate of primary alcohols can be accomplished similarly in boiling xylenes.

AB - Various S-methyl dithiocarbonates of tertiary and secondary alcohols are effectively deoxygenated in high isolated yields by treatment with diphenylphosphine oxide and various radical initiators in boiling dioxane. Deoxygenation of S-methyl dithiocarbonate of primary alcohols can be accomplished similarly in boiling xylenes.

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M3 - Article

AN - SCOPUS:0001269617

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JO - Synthetic Communications

JF - Synthetic Communications

IS - 19

ER -

Diphenylphosphine oxide: An alternative to organotin hydrides in the radical deoxygenation of alcohols

Abstract

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