Designing CdS Mesoporous Networks on Co-C@Co9S8 Double-Shelled Nanocages as Redox-Mediator-Free Z-Scheme Photocatalyst

D. Amaranatha Reddy, Hanbit Park, Madhusudana Gopannagari, Eun Hwa Kim, Seunghee Lee, D. Praveen Kumar, Tae Kyu Kim

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71 Citations (Scopus)


Designing porous nanostructures with unprecedented functionalities and an effective ability to harvest the maximum energy region of the solar spectrum and suppress the charge-carrier recombination rate offers promising potential for sustainable energy production. Although several functional porous nanostructures have been developed, high-efficiency materials are still needed. Herein, we report a new, highly active, noble-metal-free, and redox-mediator-free Z-scheme photocatalyst, CdS/Co-C@Co9S8, for H2 production through water splitting under solar irradiation. The designed photocatalytic system contains open 3 D CdS mesopores as a light absorber for wider solar-light harvesting. Metal–organicframework-derived cobalt nanocrystal-embedded few-layered carbon@Co9S8 double-shelled nanocages were used as a co-semiconductor to hamper the photo charge-carrier recombination by accelerating the photogenerated electrons and holes from the other semiconductor. The optimized catalyst shows a H2 evolution rate of 26.69 mmol g−1 h−1 under simulated solar irradiation, which is 46 times higher than that of the as-synthesized CdS mesoporous nanostructures. The apparent quantum yield reached 7.82 % at λ=425 nm in 5 h. The outstanding photocatalytic activity of CdS/Co-C@Co9S8 reflects the favorable suppression of the charge-carrier recombination rate, as determined by photoluminescence, photocurrent, and impedance analyses. We believe that the findings reported here may inspire the design of new noble-metal-free porous nanohybrids for sustainable H2 production.

Original languageEnglish
Pages (from-to)245-253
Number of pages9
Issue number1
Publication statusPublished - 2018 Jan 10

Bibliographical note

Funding Information:
This work was supported by grants from the National Research Foundation of Korea (NRF), funded by the Korean government (MSIP) (2014R1A4A1001690 and 2016R1E1A1A01941978). This research was also supported in part by the Max Planck POSTECH/ KOREA Research Initiative Program [Grant No. 2016 K1A4A4A01922028] through the MEST’s NRF funding.

Publisher Copyright:
© 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim

All Science Journal Classification (ASJC) codes

  • Environmental Chemistry
  • Chemical Engineering(all)
  • Materials Science(all)
  • Energy(all)


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