Design for a small molecule based chemosensor containing boron and pyridine moieties to detect HF

Ying Hu; Mahnseok Kye; Ji Young Jung; Yong beom Lim; Juyoung Yoon

doi:10.1016/j.snb.2017.09.072

Design for a small molecule based chemosensor containing boron and pyridine moieties to detect HF

Ying Hu, Mahnseok Kye, Ji Young Jung, Yong beom Lim, Juyoung Yoon

Department of Materials Science and Engineering

Research output: Contribution to journal › Article › peer-review

14 Citations (Scopus)

Abstract

A new triarylborane compound 1 is described as fluorescent probe for HF gas with high sensitivity and selectivity. The system utilized the coordination of a fluoride ion to the boron center in 1 to cause perturbation in the energy transfer pathway and the π conjugation, which induced distinct fluorescent quenching. A probe 1-coated film was further applied to detect HF gas via a unique capacitance change.

Original language	English
Pages (from-to)	2621-2627
Number of pages	7
Journal	Sensors and Actuators, B: Chemical
Volume	255
DOIs	https://doi.org/10.1016/j.snb.2017.09.072
Publication status	Published - 2018 Feb

Bibliographical note

Funding Information:
This study was financially supported by a grant from the National Creative Research Initiative programs of the National Research Foundation of Korea (NRF) funded by the Korean government (MSIP No. 2012R1A3A2048814). This research was also supported by NRF of Korea (MSIP No. 2017R1A2A2A05069773), Civil-Military Technology Cooperation Program, and Yonsei University Future-leading Research Initiative. Mass spectral data were obtained from the Korea Basic Science Institute (Daegu) using a Jeol JMS 700 high-resolution mass spectrometer. MHz solid state NMR spectrometer (unityINOVA, Agilent Technologies, U.S.A) at KBSI Western Seoul center. 19 F NMR and 11 B NMR data were acquired on 500

Publisher Copyright:
© 2017 Elsevier B.V.

All Science Journal Classification (ASJC) codes

Electronic, Optical and Magnetic Materials
Instrumentation
Condensed Matter Physics
Surfaces, Coatings and Films
Metals and Alloys
Electrical and Electronic Engineering
Materials Chemistry

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10.1016/j.snb.2017.09.072

Cite this

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abstract = "A new triarylborane compound 1 is described as fluorescent probe for HF gas with high sensitivity and selectivity. The system utilized the coordination of a fluoride ion to the boron center in 1 to cause perturbation in the energy transfer pathway and the π conjugation, which induced distinct fluorescent quenching. A probe 1-coated film was further applied to detect HF gas via a unique capacitance change.",

author = "Ying Hu and Mahnseok Kye and Jung, {Ji Young} and Lim, {Yong beom} and Juyoung Yoon",

note = "Funding Information: This study was financially supported by a grant from the National Creative Research Initiative programs of the National Research Foundation of Korea (NRF) funded by the Korean government (MSIP No. 2012R1A3A2048814). This research was also supported by NRF of Korea (MSIP No. 2017R1A2A2A05069773), Civil-Military Technology Cooperation Program, and Yonsei University Future-leading Research Initiative. Mass spectral data were obtained from the Korea Basic Science Institute (Daegu) using a Jeol JMS 700 high-resolution mass spectrometer. MHz solid state NMR spectrometer (unityINOVA, Agilent Technologies, U.S.A) at KBSI Western Seoul center. 19 F NMR and 11 B NMR data were acquired on 500 Publisher Copyright: {\textcopyright} 2017 Elsevier B.V.",

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doi = "10.1016/j.snb.2017.09.072",

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AU - Hu, Ying

AU - Kye, Mahnseok

AU - Jung, Ji Young

AU - Lim, Yong beom

AU - Yoon, Juyoung

N1 - Funding Information: This study was financially supported by a grant from the National Creative Research Initiative programs of the National Research Foundation of Korea (NRF) funded by the Korean government (MSIP No. 2012R1A3A2048814). This research was also supported by NRF of Korea (MSIP No. 2017R1A2A2A05069773), Civil-Military Technology Cooperation Program, and Yonsei University Future-leading Research Initiative. Mass spectral data were obtained from the Korea Basic Science Institute (Daegu) using a Jeol JMS 700 high-resolution mass spectrometer. MHz solid state NMR spectrometer (unityINOVA, Agilent Technologies, U.S.A) at KBSI Western Seoul center. 19 F NMR and 11 B NMR data were acquired on 500 Publisher Copyright: © 2017 Elsevier B.V.

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Design for a small molecule based chemosensor containing boron and pyridine moieties to detect HF

Abstract

Bibliographical note

All Science Journal Classification (ASJC) codes

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