Dependence of facilitated olefin transport on the thickness of silver polymer electrolyte membranes

Jong Hak Kim; Su Mi Park; Jongok Won; Yong Soo Kang

doi:10.1016/j.memsci.2004.02.019

Dependence of facilitated olefin transport on the thickness of silver polymer electrolyte membranes

Jong Hak Kim, Su Mi Park, Jongok Won, Yong Soo Kang

Department of Chemical and Biomolecular Engineering

Research output: Contribution to journal › Article › peer-review

17 Citations (Scopus)

Abstract

Facilitated olefin transport membranes consisting of AgBF₄ dissolved in poly(2-ethyl-2-oxazoline) (POZ) were prepared for use in propylene/propane separation. It was found that facilitated propylene transport through these membranes depends on their thickness. As the membrane thickness increases, the propylene permeability increases whereas the propane permeability remains almost constant, resulting in an increase in the membranes' selectivity of propylene over propane. The concentration fluctuation model for facilitated transport in the solid state predicts a dependence of facilitated transport on thickness. In this note, we compare the dependence of the propylene permeability of POZ/AgBF₄ membranes on their thickness with that predicted by the concentration fluctuation model.

Original language	English
Pages (from-to)	209-212
Number of pages	4
Journal	Journal of Membrane Science
Volume	236
Issue number	1-2
DOIs	https://doi.org/10.1016/j.memsci.2004.02.019
Publication status	Published - 2004 Jun 15

Bibliographical note

Funding Information:
The authors gratefully acknowledge the financial support from the Ministry of Science and Technology of Korea through the Creative Research Initiatives Program. J. Won and S.M. Park also acknowledge the financial support provided by the KOSEF (R0420020000000302002).

All Science Journal Classification (ASJC) codes

Biochemistry
Materials Science(all)
Physical and Theoretical Chemistry
Filtration and Separation

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10.1016/j.memsci.2004.02.019

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title = "Dependence of facilitated olefin transport on the thickness of silver polymer electrolyte membranes",

abstract = "Facilitated olefin transport membranes consisting of AgBF4 dissolved in poly(2-ethyl-2-oxazoline) (POZ) were prepared for use in propylene/propane separation. It was found that facilitated propylene transport through these membranes depends on their thickness. As the membrane thickness increases, the propylene permeability increases whereas the propane permeability remains almost constant, resulting in an increase in the membranes' selectivity of propylene over propane. The concentration fluctuation model for facilitated transport in the solid state predicts a dependence of facilitated transport on thickness. In this note, we compare the dependence of the propylene permeability of POZ/AgBF4 membranes on their thickness with that predicted by the concentration fluctuation model.",

author = "Kim, {Jong Hak} and Park, {Su Mi} and Jongok Won and Kang, {Yong Soo}",

note = "Funding Information: The authors gratefully acknowledge the financial support from the Ministry of Science and Technology of Korea through the Creative Research Initiatives Program. J. Won and S.M. Park also acknowledge the financial support provided by the KOSEF (R0420020000000302002).",

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doi = "10.1016/j.memsci.2004.02.019",

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AU - Kim, Jong Hak

AU - Park, Su Mi

AU - Won, Jongok

AU - Kang, Yong Soo

N1 - Funding Information: The authors gratefully acknowledge the financial support from the Ministry of Science and Technology of Korea through the Creative Research Initiatives Program. J. Won and S.M. Park also acknowledge the financial support provided by the KOSEF (R0420020000000302002).

PY - 2004/6/15

Y1 - 2004/6/15

N2 - Facilitated olefin transport membranes consisting of AgBF4 dissolved in poly(2-ethyl-2-oxazoline) (POZ) were prepared for use in propylene/propane separation. It was found that facilitated propylene transport through these membranes depends on their thickness. As the membrane thickness increases, the propylene permeability increases whereas the propane permeability remains almost constant, resulting in an increase in the membranes' selectivity of propylene over propane. The concentration fluctuation model for facilitated transport in the solid state predicts a dependence of facilitated transport on thickness. In this note, we compare the dependence of the propylene permeability of POZ/AgBF4 membranes on their thickness with that predicted by the concentration fluctuation model.

AB - Facilitated olefin transport membranes consisting of AgBF4 dissolved in poly(2-ethyl-2-oxazoline) (POZ) were prepared for use in propylene/propane separation. It was found that facilitated propylene transport through these membranes depends on their thickness. As the membrane thickness increases, the propylene permeability increases whereas the propane permeability remains almost constant, resulting in an increase in the membranes' selectivity of propylene over propane. The concentration fluctuation model for facilitated transport in the solid state predicts a dependence of facilitated transport on thickness. In this note, we compare the dependence of the propylene permeability of POZ/AgBF4 membranes on their thickness with that predicted by the concentration fluctuation model.

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Dependence of facilitated olefin transport on the thickness of silver polymer electrolyte membranes

Abstract

Bibliographical note

All Science Journal Classification (ASJC) codes

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