Decoding the Morphological Diversity in Two Dimensional Crystalline Porous Polymers by Core Planarity Modulation

Arjun Halder; Sharath Kandambeth; Bishnu P. Biswal; Gagandeep Kaur; Neha Chaki Roy; Matthew Addicoat; Jagadish K. Salunke; Subhrashis Banerjee; Kumar Vanka; Thomas Heine; Sandeep Verma; Rahul Banerjee

doi:10.1002/anie.201600087

Decoding the Morphological Diversity in Two Dimensional Crystalline Porous Polymers by Core Planarity Modulation

Arjun Halder, Sharath Kandambeth, Bishnu P. Biswal, Gagandeep Kaur, Neha Chaki Roy, Matthew Addicoat, Jagadish K. Salunke, Subhrashis Banerjee, Kumar Vanka, Thomas Heine, Sandeep Verma, Rahul Banerjee

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

104 Citations (Scopus)

Abstract

Two new chemically stable triazine- and phenyl-core-based crystalline porous polymers (CPPs) have been synthesized using a single-step template-free solvothermal route. Unique morphological diversities were observed for these CPPs [2,3-DhaTta (ribbon) and 2,3-DhaTab (hollow sphere)] by simply altering the linker planarity. A detailed time-dependent study established a significant correlation between the molecular level structures of building blocks with the morphology of CPPs. Moreover, a DFT study was done for calculating the interlayer stacking energy, which revealed that the extent of stacking efficiency is responsible for governing the morphological diversity in these CPPs.

Original language	English
Pages (from-to)	7806-7810
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	55
Issue number	27
DOIs	https://doi.org/10.1002/anie.201600087
Publication status	Published - 2016 Jun 27

Bibliographical note

Publisher Copyright:
© 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim

All Science Journal Classification (ASJC) codes

Catalysis
Chemistry(all)

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10.1002/anie.201600087

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Halder, A., Kandambeth, S., Biswal, B. P., Kaur, G., Roy, N. C., Addicoat, M., Salunke, J. K., Banerjee, S., Vanka, K., Heine, T., Verma, S., & Banerjee, R. (2016). Decoding the Morphological Diversity in Two Dimensional Crystalline Porous Polymers by Core Planarity Modulation. Angewandte Chemie - International Edition, 55(27), 7806-7810. https://doi.org/10.1002/anie.201600087

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title = "Decoding the Morphological Diversity in Two Dimensional Crystalline Porous Polymers by Core Planarity Modulation",

abstract = "Two new chemically stable triazine- and phenyl-core-based crystalline porous polymers (CPPs) have been synthesized using a single-step template-free solvothermal route. Unique morphological diversities were observed for these CPPs [2,3-DhaTta (ribbon) and 2,3-DhaTab (hollow sphere)] by simply altering the linker planarity. A detailed time-dependent study established a significant correlation between the molecular level structures of building blocks with the morphology of CPPs. Moreover, a DFT study was done for calculating the interlayer stacking energy, which revealed that the extent of stacking efficiency is responsible for governing the morphological diversity in these CPPs.",

author = "Arjun Halder and Sharath Kandambeth and Biswal, {Bishnu P.} and Gagandeep Kaur and Roy, {Neha Chaki} and Matthew Addicoat and Salunke, {Jagadish K.} and Subhrashis Banerjee and Kumar Vanka and Thomas Heine and Sandeep Verma and Rahul Banerjee",

note = "Publisher Copyright: {\textcopyright} 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim",

year = "2016",

month = jun,

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doi = "10.1002/anie.201600087",

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Halder, A, Kandambeth, S, Biswal, BP, Kaur, G, Roy, NC, Addicoat, M, Salunke, JK, Banerjee, S, Vanka, K, Heine, T, Verma, S & Banerjee, R 2016, 'Decoding the Morphological Diversity in Two Dimensional Crystalline Porous Polymers by Core Planarity Modulation', Angewandte Chemie - International Edition, vol. 55, no. 27, pp. 7806-7810. https://doi.org/10.1002/anie.201600087

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AU - Halder, Arjun

AU - Kandambeth, Sharath

AU - Biswal, Bishnu P.

AU - Kaur, Gagandeep

AU - Roy, Neha Chaki

AU - Addicoat, Matthew

AU - Salunke, Jagadish K.

AU - Banerjee, Subhrashis

AU - Vanka, Kumar

AU - Heine, Thomas

AU - Verma, Sandeep

AU - Banerjee, Rahul

PY - 2016/6/27

Y1 - 2016/6/27

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AB - Two new chemically stable triazine- and phenyl-core-based crystalline porous polymers (CPPs) have been synthesized using a single-step template-free solvothermal route. Unique morphological diversities were observed for these CPPs [2,3-DhaTta (ribbon) and 2,3-DhaTab (hollow sphere)] by simply altering the linker planarity. A detailed time-dependent study established a significant correlation between the molecular level structures of building blocks with the morphology of CPPs. Moreover, a DFT study was done for calculating the interlayer stacking energy, which revealed that the extent of stacking efficiency is responsible for governing the morphological diversity in these CPPs.

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Decoding the Morphological Diversity in Two Dimensional Crystalline Porous Polymers by Core Planarity Modulation

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