Cu(II) complex of a flexible tripodal receptor as a highly selective fluorescent probe for iodide

Narinder Singh; Hee Jung Jung; Doo Ok Jang

doi:10.1016/j.tetlet.2008.10.088

Cu(II) complex of a flexible tripodal receptor as a highly selective fluorescent probe for iodide

Narinder Singh, Hee Jung Jung, Doo Ok Jang

Chemistry and Medical Chemistry

Research output: Contribution to journal › Article › peer-review

14 Citations (Scopus)

Abstract

A Cu(II) complex of a tripodal receptor bearing an anthracene moiety on one pod as a fluorophore was synthesized. The anion recognition behavior of the Cu(II) complex was evaluated in CH₃CN/H₂O (95:5, v/v), resulting in an extremely high selectivity for iodide over other anions such as F^-, Cl^-, Br^-, NO₃^-, CH₃COO^-, and H₂ PO₂^-. The Cu(II) complex acts as a selective probe for estimating iodide even in the presence of other anions without any interference.

Original language	English
Pages (from-to)	71-74
Number of pages	4
Journal	Tetrahedron Letters
Volume	50
Issue number	1
DOIs	https://doi.org/10.1016/j.tetlet.2008.10.088
Publication status	Published - 2009 Jan 7

Bibliographical note

Funding Information:
This work was supported by the Center for Bioactive Molecular Hybrids.

All Science Journal Classification (ASJC) codes

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/j.tetlet.2008.10.088

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title = "Cu(II) complex of a flexible tripodal receptor as a highly selective fluorescent probe for iodide",

abstract = "A Cu(II) complex of a tripodal receptor bearing an anthracene moiety on one pod as a fluorophore was synthesized. The anion recognition behavior of the Cu(II) complex was evaluated in CH3CN/H2O (95:5, v/v), resulting in an extremely high selectivity for iodide over other anions such as F-, Cl-, Br-, NO3-, CH3COO-, and H2 PO2-. The Cu(II) complex acts as a selective probe for estimating iodide even in the presence of other anions without any interference.",

author = "Narinder Singh and Jung, {Hee Jung} and Jang, {Doo Ok}",

note = "Funding Information: This work was supported by the Center for Bioactive Molecular Hybrids. ",

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AU - Singh, Narinder

AU - Jung, Hee Jung

AU - Jang, Doo Ok

N1 - Funding Information: This work was supported by the Center for Bioactive Molecular Hybrids.

PY - 2009/1/7

Y1 - 2009/1/7

N2 - A Cu(II) complex of a tripodal receptor bearing an anthracene moiety on one pod as a fluorophore was synthesized. The anion recognition behavior of the Cu(II) complex was evaluated in CH3CN/H2O (95:5, v/v), resulting in an extremely high selectivity for iodide over other anions such as F-, Cl-, Br-, NO3-, CH3COO-, and H2 PO2-. The Cu(II) complex acts as a selective probe for estimating iodide even in the presence of other anions without any interference.

AB - A Cu(II) complex of a tripodal receptor bearing an anthracene moiety on one pod as a fluorophore was synthesized. The anion recognition behavior of the Cu(II) complex was evaluated in CH3CN/H2O (95:5, v/v), resulting in an extremely high selectivity for iodide over other anions such as F-, Cl-, Br-, NO3-, CH3COO-, and H2 PO2-. The Cu(II) complex acts as a selective probe for estimating iodide even in the presence of other anions without any interference.

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SN - 0040-4039

VL - 50

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JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 1

ER -

Cu(II) complex of a flexible tripodal receptor as a highly selective fluorescent probe for iodide

Abstract

Bibliographical note

All Science Journal Classification (ASJC) codes

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