Crystallization and dielectric properties of low temperature dielectrics containing Li2O filler

Won Bae Lim; Viswanathan S. Saji; Yong Soo Cho; Yong Gun Shul; Sangwoo Lim; Jae Hyuk Jang; Hong Ryul Lee

doi:10.1016/j.jnoncrysol.2008.05.014

Crystallization and dielectric properties of low temperature dielectrics containing Li₂O filler

Won Bae Lim, Viswanathan S. Saji, Yong Soo Cho, Yong Gun Shul, Sangwoo Lim, Jae Hyuk Jang, Hong Ryul Lee

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

Crystallization and dielectric properties of typical low temperature co-fired ceramics (LTCC) consisting of calcium zinc aluminoborosilicate glass and Al₂O₃ filler were investigated by substituting the Al₂O₃ filler partially with Li₂O at the levels of 2-10 wt%. Depending on the content of Li₂O, densification was found significantly affected by early crystallization that resulted from the formation of unexpected crystalline phases including LiAlSiO₄, Ca₂SiO₄, LiAlO₂, and LiAlSi₃O₈. The effect of hindering sintering via earlier crystallization became enormous regardless of firing temperature when >5 wt% Li₂O substitution occurred. It was observed that the substitution of 2 wt% Li₂O for Al₂O₃ was beneficial in producing promising performance at the low temperature of 750 °C, which can be highlighted with k ∼ 8.7 and tan δ ∼ 0.009 at 1 MHz.

Original language	English
Pages (from-to)	3849-3853
Number of pages	5
Journal	Journal of Non-Crystalline Solids
Volume	354
Issue number	32
DOIs	https://doi.org/10.1016/j.jnoncrysol.2008.05.014
Publication status	Published - 2008 Aug 15

Bibliographical note

Funding Information:
This work is supported through a research project by the Korean Ministry of Commerce, Industry and Energy.

All Science Journal Classification (ASJC) codes

Electronic, Optical and Magnetic Materials
Ceramics and Composites
Condensed Matter Physics
Materials Chemistry

Access to Document

10.1016/j.jnoncrysol.2008.05.014

Cite this

@article{6357d495b5cd49c186130b88cf05abad,

title = "Crystallization and dielectric properties of low temperature dielectrics containing Li2O filler",

abstract = "Crystallization and dielectric properties of typical low temperature co-fired ceramics (LTCC) consisting of calcium zinc aluminoborosilicate glass and Al2O3 filler were investigated by substituting the Al2O3 filler partially with Li2O at the levels of 2-10 wt%. Depending on the content of Li2O, densification was found significantly affected by early crystallization that resulted from the formation of unexpected crystalline phases including LiAlSiO4, Ca2SiO4, LiAlO2, and LiAlSi3O8. The effect of hindering sintering via earlier crystallization became enormous regardless of firing temperature when >5 wt% Li2O substitution occurred. It was observed that the substitution of 2 wt% Li2O for Al2O3 was beneficial in producing promising performance at the low temperature of 750 °C, which can be highlighted with k ∼ 8.7 and tan δ ∼ 0.009 at 1 MHz.",

author = "Lim, {Won Bae} and Saji, {Viswanathan S.} and Cho, {Yong Soo} and Shul, {Yong Gun} and Sangwoo Lim and Jang, {Jae Hyuk} and Lee, {Hong Ryul}",

note = "Funding Information: This work is supported through a research project by the Korean Ministry of Commerce, Industry and Energy. ",

year = "2008",

month = aug,

day = "15",

doi = "10.1016/j.jnoncrysol.2008.05.014",

language = "English",

volume = "354",

pages = "3849--3853",

journal = "Journal of Non-Crystalline Solids",

issn = "0022-3093",

publisher = "Elsevier",

number = "32",

}

TY - JOUR

T1 - Crystallization and dielectric properties of low temperature dielectrics containing Li2O filler

AU - Lim, Won Bae

AU - Saji, Viswanathan S.

AU - Cho, Yong Soo

AU - Shul, Yong Gun

AU - Lim, Sangwoo

AU - Jang, Jae Hyuk

AU - Lee, Hong Ryul

N1 - Funding Information: This work is supported through a research project by the Korean Ministry of Commerce, Industry and Energy.

PY - 2008/8/15

Y1 - 2008/8/15

N2 - Crystallization and dielectric properties of typical low temperature co-fired ceramics (LTCC) consisting of calcium zinc aluminoborosilicate glass and Al2O3 filler were investigated by substituting the Al2O3 filler partially with Li2O at the levels of 2-10 wt%. Depending on the content of Li2O, densification was found significantly affected by early crystallization that resulted from the formation of unexpected crystalline phases including LiAlSiO4, Ca2SiO4, LiAlO2, and LiAlSi3O8. The effect of hindering sintering via earlier crystallization became enormous regardless of firing temperature when >5 wt% Li2O substitution occurred. It was observed that the substitution of 2 wt% Li2O for Al2O3 was beneficial in producing promising performance at the low temperature of 750 °C, which can be highlighted with k ∼ 8.7 and tan δ ∼ 0.009 at 1 MHz.

AB - Crystallization and dielectric properties of typical low temperature co-fired ceramics (LTCC) consisting of calcium zinc aluminoborosilicate glass and Al2O3 filler were investigated by substituting the Al2O3 filler partially with Li2O at the levels of 2-10 wt%. Depending on the content of Li2O, densification was found significantly affected by early crystallization that resulted from the formation of unexpected crystalline phases including LiAlSiO4, Ca2SiO4, LiAlO2, and LiAlSi3O8. The effect of hindering sintering via earlier crystallization became enormous regardless of firing temperature when >5 wt% Li2O substitution occurred. It was observed that the substitution of 2 wt% Li2O for Al2O3 was beneficial in producing promising performance at the low temperature of 750 °C, which can be highlighted with k ∼ 8.7 and tan δ ∼ 0.009 at 1 MHz.

UR - http://www.scopus.com/inward/record.url?scp=46849119234&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=46849119234&partnerID=8YFLogxK

U2 - 10.1016/j.jnoncrysol.2008.05.014

DO - 10.1016/j.jnoncrysol.2008.05.014

M3 - Article

AN - SCOPUS:46849119234

SN - 0022-3093

VL - 354

SP - 3849

EP - 3853

JO - Journal of Non-Crystalline Solids

JF - Journal of Non-Crystalline Solids

IS - 32

ER -