Correlation between volumetric change and glass-forming ability of metallic glass-forming alloys

E. S. Park; D. H. Kim

doi:10.1063/1.2889442

Correlation between volumetric change and glass-forming ability of metallic glass-forming alloys

E. S. Park, D. H. Kim

Department of Materials Science and Engineering

Research output: Contribution to journal › Article › peer-review

24 Citations (Scopus)

Abstract

We draw attention to the relationship between volumetric change and glass-forming ability (GFA) in various metallic glass-forming alloys. The critical cooling rate can be expressed as Rc =2.5× 10-5 exp (5.0× 102 Vlg), where Vlg is defined as (Vl - Vg) Vl. We specifically plot the temperature dependence of specific volume for Ca65 Mg15 Zn20 alloy, and then demonstrate that the larger slope between Vl and Vg, closely related to thermal expansion coefficient, corresponds well to the GFA of the alloy. This insight can provide a clue if the correlations are to be used in the appreciation of glass formation and in the development of an alloy system with enhanced GFA.

Original language	English
Article number	091915
Journal	Applied Physics Letters
Volume	92
Issue number	9
DOIs	https://doi.org/10.1063/1.2889442
Publication status	Published - 2008

Bibliographical note

Funding Information:
This work was supported by the Global Research Laboratory of the Korean Ministry of Science. One of the author (E.S.P.) was supported by the Korea Research foundation Grant funded by the Korean Government (MOEHRD) (KRF-2006-214-D00066). The authors are indebted to Professor Frans Spaepen of Harvard University for thoughtful advice.

All Science Journal Classification (ASJC) codes

Physics and Astronomy (miscellaneous)

Access to Document

10.1063/1.2889442

Cite this

@article{c3d00ecda93f4c2e80b83dda66962c36,

title = "Correlation between volumetric change and glass-forming ability of metallic glass-forming alloys",

abstract = "We draw attention to the relationship between volumetric change and glass-forming ability (GFA) in various metallic glass-forming alloys. The critical cooling rate can be expressed as Rc =2.5× 10-5 exp (5.0× 102 Vlg), where Vlg is defined as (Vl - Vg) Vl. We specifically plot the temperature dependence of specific volume for Ca65 Mg15 Zn20 alloy, and then demonstrate that the larger slope between Vl and Vg, closely related to thermal expansion coefficient, corresponds well to the GFA of the alloy. This insight can provide a clue if the correlations are to be used in the appreciation of glass formation and in the development of an alloy system with enhanced GFA.",

author = "Park, {E. S.} and Kim, {D. H.}",

note = "Funding Information: This work was supported by the Global Research Laboratory of the Korean Ministry of Science. One of the author (E.S.P.) was supported by the Korea Research foundation Grant funded by the Korean Government (MOEHRD) (KRF-2006-214-D00066). The authors are indebted to Professor Frans Spaepen of Harvard University for thoughtful advice.",

year = "2008",

doi = "10.1063/1.2889442",

language = "English",

volume = "92",

journal = "Applied Physics Letters",

issn = "0003-6951",

publisher = "American Institute of Physics Publising LLC",

number = "9",

}

TY - JOUR

T1 - Correlation between volumetric change and glass-forming ability of metallic glass-forming alloys

AU - Park, E. S.

AU - Kim, D. H.

N1 - Funding Information: This work was supported by the Global Research Laboratory of the Korean Ministry of Science. One of the author (E.S.P.) was supported by the Korea Research foundation Grant funded by the Korean Government (MOEHRD) (KRF-2006-214-D00066). The authors are indebted to Professor Frans Spaepen of Harvard University for thoughtful advice.

PY - 2008

Y1 - 2008

N2 - We draw attention to the relationship between volumetric change and glass-forming ability (GFA) in various metallic glass-forming alloys. The critical cooling rate can be expressed as Rc =2.5× 10-5 exp (5.0× 102 Vlg), where Vlg is defined as (Vl - Vg) Vl. We specifically plot the temperature dependence of specific volume for Ca65 Mg15 Zn20 alloy, and then demonstrate that the larger slope between Vl and Vg, closely related to thermal expansion coefficient, corresponds well to the GFA of the alloy. This insight can provide a clue if the correlations are to be used in the appreciation of glass formation and in the development of an alloy system with enhanced GFA.

AB - We draw attention to the relationship between volumetric change and glass-forming ability (GFA) in various metallic glass-forming alloys. The critical cooling rate can be expressed as Rc =2.5× 10-5 exp (5.0× 102 Vlg), where Vlg is defined as (Vl - Vg) Vl. We specifically plot the temperature dependence of specific volume for Ca65 Mg15 Zn20 alloy, and then demonstrate that the larger slope between Vl and Vg, closely related to thermal expansion coefficient, corresponds well to the GFA of the alloy. This insight can provide a clue if the correlations are to be used in the appreciation of glass formation and in the development of an alloy system with enhanced GFA.

UR - http://www.scopus.com/inward/record.url?scp=40549137122&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=40549137122&partnerID=8YFLogxK

U2 - 10.1063/1.2889442

DO - 10.1063/1.2889442

M3 - Article

AN - SCOPUS:40549137122

SN - 0003-6951

VL - 92

JO - Applied Physics Letters

JF - Applied Physics Letters

IS - 9

M1 - 091915

ER -

Correlation between volumetric change and glass-forming ability of metallic glass-forming alloys

Abstract

Bibliographical note

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this