Core-shell nanostructured heteropoly acid-functionalized metal-organic frameworks: Bifunctional heterogeneous catalyst for efficient biodiesel production

Yukwon Jeon, Won Seok Chi, Jusoon Hwang, Do Hyun Kim, Jong Hak Kim, Yong Gun Shul

Research output: Contribution to journalArticlepeer-review

102 Citations (Scopus)


We developed a new class of acid-base bifunctional heterogeneous catalyst, which can be used in the transesterification of rapeseed oil for highly efficient biodiesel production. A simple Keggin-type HPA (heteropoly acid) functionalization on the surface of zeolitic imidazolate framework-8 (ZIF-8) nanoparticles, through an imidazolium medium, results in the bifunctional heterogeneous catalysts. The hybrid materials exhibit a novel hierarchically core-shell nanostructure, which provides a large surface area and interconnectivity, leading to a thin-wrinkled HPA shell at the surface of rhombic dodecahedral ZIF-8 core crystals. A strong O–N hybrid bonding through an electrostatic effect in the hybrid materials demonstrates a strong interaction between the Keggin and imidazole units, which is one of the main driving forces of hybrid materials formation. Additionally, the transformation of the HPA/ZIF-8 ratio in the hybrid materials changes the acidity and basicity, thereby affecting catalyst activity. We used these bifunctional core-shell materials as environmentally friendly heterogeneous catalysts in the transesterification of rapeseed oil with methanol to produce a high-quality biodiesel. Of particular interest, the HPA-functionalized ZIF-8 catalyst with a proper HPA/ZIF-8 ratio shows a high FAME conversion of 98.02% along with high recyclability because of the sufficiently large surface area and bi-functionality of strong acidity. Furthermore, the HPA-functionalized ZIF-8 catalyst shows a high reaction efficiency of the benzyl alcohol oxidation process, indicating a great potential of our catalyst to a wide range of applications.

Original languageEnglish
Pages (from-to)51-59
Number of pages9
JournalApplied Catalysis B: Environmental
Publication statusPublished - 2019 Mar

Bibliographical note

Funding Information:
This work was supported by the New and Renewable Energy R&D Program (Grant 20113020030020 ) under the Ministry of Knowledge Economy and the National Research Foundation (NRF) of South Korea grant funded by the Ministry of Science, ICT and Future Planning ( NRF-2017R1A4A1014569 , NRF-2017R1D1A1B06028030 , NRF-2018M3A7B4071535 ).

Publisher Copyright:
© 2018 Elsevier B.V.

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Environmental Science(all)
  • Process Chemistry and Technology


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