Control of the conformational dynamics of meso-meso vinylene-bridged Zn(ii) porphyrin dimers through diamine coordination

Minjung Son; Young Mo Sung; Sumito Tokuji; Norihito Fukui; Hideki Yorimitsu; Atsuhiro Osuka; Dongho Kim

doi:10.1039/c4cc00126e

Control of the conformational dynamics of meso-meso vinylene-bridged Zn(ii) porphyrin dimers through diamine coordination

Minjung Son, Young Mo Sung, Sumito Tokuji, Norihito Fukui, Hideki Yorimitsu, Atsuhiro Osuka, Dongho Kim

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

16 Citations (Scopus)

Abstract

Two meso-meso vinylene-bridged Zn(ii) porphyrin dimers 1 and 2 were analyzed in terms of the control of their conformational dynamics induced by the rotation around the double bond bridge. The dihedral angles between the two porphyrin rings were modulated through coordination with α,ω-diaminoalkanes of varying chain lengths.

Original language	English
Pages (from-to)	3078-3080
Number of pages	3
Journal	Chemical Communications
Volume	50
Issue number	23
DOIs	https://doi.org/10.1039/c4cc00126e
Publication status	Published - 2014 Feb 20

All Science Journal Classification (ASJC) codes

Electronic, Optical and Magnetic Materials
Ceramics and Composites
Metals and Alloys
Materials Chemistry
Surfaces, Coatings and Films
Chemistry(all)
Catalysis

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abstract = "Two meso-meso vinylene-bridged Zn(ii) porphyrin dimers 1 and 2 were analyzed in terms of the control of their conformational dynamics induced by the rotation around the double bond bridge. The dihedral angles between the two porphyrin rings were modulated through coordination with α,ω-diaminoalkanes of varying chain lengths.",

author = "Minjung Son and Sung, {Young Mo} and Sumito Tokuji and Norihito Fukui and Hideki Yorimitsu and Atsuhiro Osuka and Dongho Kim",

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AU - Son, Minjung

AU - Sung, Young Mo

AU - Tokuji, Sumito

AU - Fukui, Norihito

AU - Yorimitsu, Hideki

AU - Osuka, Atsuhiro

AU - Kim, Dongho

PY - 2014/2/20

Y1 - 2014/2/20

N2 - Two meso-meso vinylene-bridged Zn(ii) porphyrin dimers 1 and 2 were analyzed in terms of the control of their conformational dynamics induced by the rotation around the double bond bridge. The dihedral angles between the two porphyrin rings were modulated through coordination with α,ω-diaminoalkanes of varying chain lengths.

AB - Two meso-meso vinylene-bridged Zn(ii) porphyrin dimers 1 and 2 were analyzed in terms of the control of their conformational dynamics induced by the rotation around the double bond bridge. The dihedral angles between the two porphyrin rings were modulated through coordination with α,ω-diaminoalkanes of varying chain lengths.

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U2 - 10.1039/c4cc00126e

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JF - Chemical Communications

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ER -

Control of the conformational dynamics of meso-meso vinylene-bridged Zn(ii) porphyrin dimers through diamine coordination

Abstract

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