Composition-Dependent Hot Carrier Relaxation Dynamics in Cesium Lead Halide (CsPbX3, X=Br and I) Perovskite Nanocrystals

Heejae Chung; Seok Il Jung; Hyo Jin Kim; Wonhee Cha; Eunji Sim; Dongho Kim; Weon Kyu Koh; Jiwon Kim

doi:10.1002/anie.201611916

Composition-Dependent Hot Carrier Relaxation Dynamics in Cesium Lead Halide (CsPbX₃, X=Br and I) Perovskite Nanocrystals

Heejae Chung, Seok Il Jung, Hyo Jin Kim, Wonhee Cha, Eunji Sim, Dongho Kim, Weon Kyu Koh, Jiwon Kim

Research output: Contribution to journal › Article › peer-review

130 Citations (Scopus)

Abstract

Cesium-based perovskite nanocrystals (NCs) have outstanding photophysical properties improving the performances of lighting devices. Fundamental studies on excitonic properties and hot-carrier dynamics in perovskite NCs further suggest that these materials show higher efficiencies compared to the bulk form of perovskites. However, the relaxation rates and pathways of hot-carriers are still being elucidated. By using ultrafast transient spectroscopy and calculating electronic band structures, we investigated the dependence of halide in Cs-based perovskite (CsPbX₃ with X=Br, I, or their mixtures) NCs on the hot-carrier relaxation processes. All samples exhibit ultrafast (<0.6 ps) hot-carrier relaxation dynamics with following order: CsPbBr₃ (310 fs)>CsPbBr_1.5I_1.5 (380 fs)>CsPbI₃ NC (580 fs). These result accounts for a reduced light emission efficiency of CsPbI₃ NC compared to CsPbBr₃ NC.

Original language	English
Pages (from-to)	4160-4164
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	56
Issue number	15
DOIs	https://doi.org/10.1002/anie.201611916
Publication status	Published - 2017 Apr 3

Bibliographical note

Funding Information:
This research was supported by the MSIP (Ministry of Science, ICT and Future Planning), Korea, under the “ICT Consilience Creative Program” (IITP-R0346-16-1008) supervised by the IITP (Institute for Information & Communications Technology Promotion. This work was also supported by the National Research Foundation of Korea (NRF) grant funded by the Korea government (MSIP) (No. 2016R1C1B1009709) and by the Industrial Technology Innovation Program (No. 10062161, ES) of MOTIE.

Publisher Copyright:
© 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim

All Science Journal Classification (ASJC) codes

Catalysis
Chemistry(all)

Access to Document

10.1002/anie.201611916

Cite this

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title = "Composition-Dependent Hot Carrier Relaxation Dynamics in Cesium Lead Halide (CsPbX3, X=Br and I) Perovskite Nanocrystals",

abstract = "Cesium-based perovskite nanocrystals (NCs) have outstanding photophysical properties improving the performances of lighting devices. Fundamental studies on excitonic properties and hot-carrier dynamics in perovskite NCs further suggest that these materials show higher efficiencies compared to the bulk form of perovskites. However, the relaxation rates and pathways of hot-carriers are still being elucidated. By using ultrafast transient spectroscopy and calculating electronic band structures, we investigated the dependence of halide in Cs-based perovskite (CsPbX3 with X=Br, I, or their mixtures) NCs on the hot-carrier relaxation processes. All samples exhibit ultrafast (<0.6 ps) hot-carrier relaxation dynamics with following order: CsPbBr3 (310 fs)>CsPbBr1.5I1.5 (380 fs)>CsPbI3 NC (580 fs). These result accounts for a reduced light emission efficiency of CsPbI3 NC compared to CsPbBr3 NC.",

author = "Heejae Chung and Jung, {Seok Il} and Kim, {Hyo Jin} and Wonhee Cha and Eunji Sim and Dongho Kim and Koh, {Weon Kyu} and Jiwon Kim",

note = "Funding Information: This research was supported by the MSIP (Ministry of Science, ICT and Future Planning), Korea, under the “ICT Consilience Creative Program” (IITP-R0346-16-1008) supervised by the IITP (Institute for Information & Communications Technology Promotion. This work was also supported by the National Research Foundation of Korea (NRF) grant funded by the Korea government (MSIP) (No. 2016R1C1B1009709) and by the Industrial Technology Innovation Program (No. 10062161, ES) of MOTIE. Publisher Copyright: {\textcopyright} 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim",

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AU - Cha, Wonhee

AU - Sim, Eunji

AU - Kim, Dongho

AU - Koh, Weon Kyu

AU - Kim, Jiwon

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Y1 - 2017/4/3

N2 - Cesium-based perovskite nanocrystals (NCs) have outstanding photophysical properties improving the performances of lighting devices. Fundamental studies on excitonic properties and hot-carrier dynamics in perovskite NCs further suggest that these materials show higher efficiencies compared to the bulk form of perovskites. However, the relaxation rates and pathways of hot-carriers are still being elucidated. By using ultrafast transient spectroscopy and calculating electronic band structures, we investigated the dependence of halide in Cs-based perovskite (CsPbX3 with X=Br, I, or their mixtures) NCs on the hot-carrier relaxation processes. All samples exhibit ultrafast (<0.6 ps) hot-carrier relaxation dynamics with following order: CsPbBr3 (310 fs)>CsPbBr1.5I1.5 (380 fs)>CsPbI3 NC (580 fs). These result accounts for a reduced light emission efficiency of CsPbI3 NC compared to CsPbBr3 NC.

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