Comparative study on partial oxidation of methane over Ni/ZrO₂, Ni/CeO₂ and Ni/Ce-ZrO₂ catalysts

The partial oxidation of methane has been studied by sequential pulse experiments with CH₄ → O₂ → CH₄ and simultaneous pulse reaction of CH₄/O₂ (2/1) over Ni/CeO₂ and Ni/Ce-ZrO₂ catalysts. Over Ni/CeO₂, CH₄ dissociates on Ni and the resultant carbon species quickly migrate to the interface of Ni-CeO₂, and then react with lattice oxygen of CeO₂ to form CO. A synergistic effect between Ni and CeO₂ support contributes to CH₄ conversion. Over Ni/ZrO₂, CH₄ and O₂ activated on the surface of metallic Ni, and then adsorbed carbon reacts with adsorbed oxygen to produce CO, which is composed of the main path for the partial oxidation of methane. The addition of ceria to zirconia enhances CH₄ dissociation and improves the carbon storage capacity. Moreover, it increases the storage capacity and mobility of oxygen in the catalyst, thus promoting carbon elimination.