TY - JOUR
T1 - Comparative resin kinetics using in situ fluorescence measurements
AU - Walsh, Daniel P.
AU - Pang, Christopher
AU - Parikh, Puja B.
AU - Kim, Young Soo
AU - Chang, Young Tae
PY - 2002/5
Y1 - 2002/5
N2 - The aminolysis of a novel activated ester resin was utilized for kinetic study via continuous in situ fluorescence measurements. A variety of resin compositions (polystyrene, JandaJel, ArgoPore, TentaGel, NovaGel, and PEGA) and solvents (dimethylformamide, acetonitrile, tetrahydrofuran, 1,2-dichlorethane, and toluene) were tested to compare their effects on the reaction rate. A linear relationship between the reaction rate and (solvent polarity x swelling of resin) was elucidated for the aminolysis reaction.
AB - The aminolysis of a novel activated ester resin was utilized for kinetic study via continuous in situ fluorescence measurements. A variety of resin compositions (polystyrene, JandaJel, ArgoPore, TentaGel, NovaGel, and PEGA) and solvents (dimethylformamide, acetonitrile, tetrahydrofuran, 1,2-dichlorethane, and toluene) were tested to compare their effects on the reaction rate. A linear relationship between the reaction rate and (solvent polarity x swelling of resin) was elucidated for the aminolysis reaction.
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U2 - 10.1021/cc010063t
DO - 10.1021/cc010063t
M3 - Article
C2 - 12005479
AN - SCOPUS:0000202085
SN - 2156-8952
VL - 4
SP - 204
EP - 208
JO - Journal of Combinatorial Chemistry
JF - Journal of Combinatorial Chemistry
IS - 3
ER -